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• W2316800661 endingPage "1590" @default.
• W2316800661 startingPage "1584" @default.
• W2316800661 abstract "Cationic copper(I) dicarbonyl complexes supported by N-heterocyclic carbene ligands, SIPr and IPr*, have been synthesized. [(SIPr)Cu(CO)2][SbF6] and [(IPr*)Cu(CO)2][SbF6] have a trigonal planar, three-coordinate copper atom with an average Cu–CO distance of 1.915 Å and display C–O stretching frequencies higher than that of the free CO (2143 cm–1). The high CO stretching frequencies suggest that the Cu(I)–CO interaction in these cationic adducts is dominated by electrostatic and OC → Cu σ-donor components. [(SIPr)Cu(CO)2][SbF6] and [(IPr*)Cu(CO)2][SbF6] readily form the corresponding [(SIPr)Cu(CO)(H2O)][SbF6] and [(IPr*)Cu(CO)(H2O)][SbF6] with loss of a CO even with traces of water, but they can be converted back to the dicarbonyl adducts using excess CO. The synthesis and structure of [(IPr*)Cu(H2O)][SbF6] are also reported. It is a two-coordinate copper adduct with a Cu–O distance of 1.874(2) Å. It reacts with excess CO to form [(IPr*)Cu(CO)2][SbF6]." @default.
• W2316800661 created "2016-06-24" @default.
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• W2316800661 date "2013-01-22" @default.
• W2316800661 modified "2023-10-13" @default.
• W2316800661 title "Isolable, Copper(I) Dicarbonyl Complexes Supported by <i>N</i>-Heterocyclic Carbenes" @default.
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• W2316800661 doi "https://doi.org/10.1021/ic302455y" @default.
• W2316800661 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23339443" @default.
• W2316800661 hasPublicationYear "2013" @default.
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