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- W2316830688 abstract "The reactive uptake of isoprene-derived epoxydiols (IEPOX) is thought to be a significant source of atmospheric secondary organic aerosol (SOA). However, the IEPOX reaction probability (γIEPOX) and its dependence upon particle composition remain poorly constrained. We report measurements of γIEPOX for trans-β-IEPOX, the predominant IEPOX isomer, on submicron particles as a function of composition, acidity, and relative humidity (RH). Particle acidity had the strongest effect. γIEPOX is more than 500 times greater on ammonium bisulfate (γ ∼ 0.05) than on ammonium sulfate (γ ≤ 1 × 10–4). We could accurately predict γIEPOX using an acid-catalyzed, epoxide ring-opening mechanism and a high Henry’s law coefficient (1.7 × 108 M/atm). Suppression of γIEPOX was observed on particles containing both ammonium bisulfate and poly(ethylene glycol) (PEG-300), likely due to diffusion and solubility limitations within a PEG-300 coating, suggesting that IEPOX uptake could be self-limiting. Using the measured uptake kinetics, the predicted atmospheric lifetime of IEPOX is a few hours in the presence of highly acidic particles (pH < 0) but is greater than 25 h on less acidic particles (pH > 3). This work highlights the importance of aerosol acidity for accurately predicting the fate of IEPOX and anthropogenically influenced biogenic SOA formation." @default.
- W2316830688 created "2016-06-24" @default.
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- W2316830688 date "2014-09-24" @default.
- W2316830688 modified "2023-10-03" @default.
- W2316830688 title "Reactive Uptake of an Isoprene-Derived Epoxydiol to Submicron Aerosol Particles" @default.
- W2316830688 cites W1966779205 @default.
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- W2316830688 cites W1978130957 @default.
- W2316830688 cites W1978848700 @default.
- W2316830688 cites W1983813775 @default.
- W2316830688 cites W1984484393 @default.
- W2316830688 cites W1987244498 @default.
- W2316830688 cites W1992510464 @default.
- W2316830688 cites W1993094858 @default.
- W2316830688 cites W1995254834 @default.
- W2316830688 cites W1997570845 @default.
- W2316830688 cites W1998232015 @default.
- W2316830688 cites W2002570697 @default.
- W2316830688 cites W2018296170 @default.
- W2316830688 cites W202440244 @default.
- W2316830688 cites W2036760300 @default.
- W2316830688 cites W2038858025 @default.
- W2316830688 cites W2041821245 @default.
- W2316830688 cites W2045617521 @default.
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- W2316830688 cites W2317030647 @default.
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- W2316830688 doi "https://doi.org/10.1021/es5034266" @default.
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