Matches in SemOpenAlex for { <https://semopenalex.org/work/W2316875293> ?p ?o ?g. }
- W2316875293 endingPage "7332" @default.
- W2316875293 startingPage "7321" @default.
- W2316875293 abstract "Copolymer composition distribution (CCD) is an important parameter of chain microstructure that has significant impact on the material properties of polymer products. Controlled/living radical polymerization (CLRP) has provided a great opportunity in producing polymers with predesigned CCDs through a model-based monomer feeding policy (MMFP) in homogeneous systems. In this work, the MMFP has been expanded to heterogeneous systems. Reversible addition–fragmentation transfer (RAFT) mini-emulsion polymerizations of styrene (St) and butyl acrylate (BA) were carried out with 3-benzyltrithiocarbonyl propionic acid (BCPA) used as a RAFT agent. A kinetic model was developed and correlated to the batch St/BA RAFT mini-emulsion experimental data for parameter estimation. The MMFP was then developed by combining the kinetic model with a semibatch reactor model and applied to the semibatch St/BA RAFT mini-emulsion copolymerization for the synthesis of targeted CCDs. The model agreed well with the polymerization kinetics. A series of St/BA copolymers with predesigned CCDs were successfully synthesized." @default.
- W2316875293 created "2016-06-24" @default.
- W2316875293 creator A5013697180 @default.
- W2316875293 creator A5036173839 @default.
- W2316875293 creator A5046978138 @default.
- W2316875293 creator A5063410413 @default.
- W2316875293 creator A5068854747 @default.
- W2316875293 date "2014-04-16" @default.
- W2316875293 modified "2023-10-18" @default.
- W2316875293 title "Targeting Copolymer Composition Distribution via Model-Based Monomer Feeding Policy in Semibatch RAFT Mini-Emulsion Copolymerization of Styrene and Butyl Acrylate" @default.
- W2316875293 cites W1964567910 @default.
- W2316875293 cites W1969617866 @default.
- W2316875293 cites W1972639446 @default.
- W2316875293 cites W1975731951 @default.
- W2316875293 cites W1976233240 @default.
- W2316875293 cites W1976721278 @default.
- W2316875293 cites W1983419216 @default.
- W2316875293 cites W1984148912 @default.
- W2316875293 cites W1985248723 @default.
- W2316875293 cites W1986178899 @default.
- W2316875293 cites W1988960812 @default.
- W2316875293 cites W1991073506 @default.
- W2316875293 cites W1997428654 @default.
- W2316875293 cites W2008060458 @default.
- W2316875293 cites W2009221741 @default.
- W2316875293 cites W2010627519 @default.
- W2316875293 cites W2017777148 @default.
- W2316875293 cites W2020407639 @default.
- W2316875293 cites W2023818992 @default.
- W2316875293 cites W2024414343 @default.
- W2316875293 cites W2025406591 @default.
- W2316875293 cites W2029838204 @default.
- W2316875293 cites W2030291402 @default.
- W2316875293 cites W2033235162 @default.
- W2316875293 cites W2033658308 @default.
- W2316875293 cites W2034701271 @default.
- W2316875293 cites W2035858397 @default.
- W2316875293 cites W2036062366 @default.
- W2316875293 cites W2038638986 @default.
- W2316875293 cites W2040515873 @default.
- W2316875293 cites W2040851781 @default.
- W2316875293 cites W2041270217 @default.
- W2316875293 cites W2042184328 @default.
- W2316875293 cites W2042205102 @default.
- W2316875293 cites W2047588656 @default.
- W2316875293 cites W2050400080 @default.
- W2316875293 cites W2055393399 @default.
- W2316875293 cites W2062066857 @default.
- W2316875293 cites W2062664418 @default.
- W2316875293 cites W2063226196 @default.
- W2316875293 cites W2064303080 @default.
- W2316875293 cites W2068463986 @default.
- W2316875293 cites W2072412787 @default.
- W2316875293 cites W2074554162 @default.
- W2316875293 cites W2081361953 @default.
- W2316875293 cites W2083285785 @default.
- W2316875293 cites W2084062951 @default.
- W2316875293 cites W2084562595 @default.
- W2316875293 cites W2086989865 @default.
- W2316875293 cites W2089986508 @default.
- W2316875293 cites W2091204719 @default.
- W2316875293 cites W2091723689 @default.
- W2316875293 cites W2092246866 @default.
- W2316875293 cites W2093833530 @default.
- W2316875293 cites W2099157047 @default.
- W2316875293 cites W2100298794 @default.
- W2316875293 cites W2100590193 @default.
- W2316875293 cites W2105260137 @default.
- W2316875293 cites W2106898997 @default.
- W2316875293 cites W2122762332 @default.
- W2316875293 cites W2123058592 @default.
- W2316875293 cites W2125858561 @default.
- W2316875293 cites W2128987968 @default.
- W2316875293 cites W2131106901 @default.
- W2316875293 cites W2132449398 @default.
- W2316875293 cites W2136380772 @default.
- W2316875293 cites W2140780122 @default.
- W2316875293 cites W2150184000 @default.
- W2316875293 cites W2152783510 @default.
- W2316875293 cites W2155653252 @default.
- W2316875293 cites W2160540872 @default.
- W2316875293 cites W2170020824 @default.
- W2316875293 cites W2320432998 @default.
- W2316875293 cites W2323700349 @default.
- W2316875293 cites W2323720438 @default.
- W2316875293 cites W2324969323 @default.
- W2316875293 cites W4211263050 @default.
- W2316875293 cites W4256667536 @default.
- W2316875293 cites W1993212127 @default.
- W2316875293 doi "https://doi.org/10.1021/ie402799u" @default.
- W2316875293 hasPublicationYear "2014" @default.
- W2316875293 type Work @default.
- W2316875293 sameAs 2316875293 @default.
- W2316875293 citedByCount "26" @default.
- W2316875293 countsByYear W23168752932014 @default.
- W2316875293 countsByYear W23168752932015 @default.
- W2316875293 countsByYear W23168752932016 @default.
- W2316875293 countsByYear W23168752932017 @default.