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- W2316875786 abstract "In the present work, significantly various structures connected by Al–O/OH/acetate–Al bonds were synthesized in a versatile sol–gel route. The various bond systems result in several three-dimensional (e.g., fibrous, highly porous, and compact) macrostructures. The shared acetate and OH ions provide the fibrous character; the shared OH ions and oxygen-bridges between octahedral Al(III) ions assist in the formation of a porous network; and the oxygen-bridges between differently (octa-, tetra-, and pentahedrally) coordinated Al(III) ions characterize the compact structures. The newly developed synthesis route is a fast and low-energy consumption sol–gel technique. This method applies only two starting materials and does not adopt any basic agent or catalyst. The synthesis is fast because it does not require any time-consuming peptization; a 3-D network forms directly from the initial solution. The low energy consumption arises from the low temperature of reactions (80 °C) and heat treatment (400–600 °C)." @default.
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- W2316875786 date "2013-10-25" @default.
- W2316875786 modified "2023-10-18" @default.
- W2316875786 title "Various Three-Dimensional Structures Connected by Al–O/OH/Acetate–Al Bonds" @default.
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- W2316875786 doi "https://doi.org/10.1021/ic402189c" @default.
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