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• W2316884082 abstract "The gas-phase reaction of methacrolein with the OH radical, in the presence of NOx, was investigated at 298 ± 2 K and atmospheric pressure of air. Hydroxyacetone, methylglyoxal, a peroxyacyl nitrate identified as CH2  C(CH3)C(O)OONO2 (peroxymethacryloyl nitrate), formaldehyde, CO, and CO2 were observed to be the major products. The product yield data for these compounds show that OH radical addition to the >C  C< bond accounts for ca. 50% of the overall reaction, with the remaining ca. 50% proceeding via H—atom abstraction from the CHO group. The data suggest that the alkoxy radical formed following the addition of OH to the terminal carbon atom, decomposes primarily to give the formyl radical plus hydroxyacetone. A lower limit ratio of 5: 1 has been estimated for OH radical addition to the terminal carbon atom of the double bond relative to addition on the inner carbon atom." @default.
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• W2316884082 date "1990-06-01" @default.
• W2316884082 modified "2023-10-17" @default.
• W2316884082 title "A product study of the gas-phase reaction of Methacrolein with the OH radical in the presence of NOx" @default.
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• W2316884082 doi "https://doi.org/10.1002/kin.550220604" @default.
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