Matches in SemOpenAlex for { <https://semopenalex.org/work/W2316912673> ?p ?o ?g. }
Showing items 1 to 81 of
81
with 100 items per page.
- W2316912673 endingPage "995" @default.
- W2316912673 startingPage "983" @default.
- W2316912673 abstract "We have observed and measured five rotational components of the 21–17 band in the HD+ molecular ion. The highest bound rotational level in υ=21 is predicted to be N = 3, which lies only 1·8 cm−1 below the H++D dissociation limit, and we have observed transitions involving all four rotational levels of υ=21. The measured transition frequencies are close to those predicted by recent non-adiabatic calculations. Each vibration-rotation line is split into six hyperfine components, which arise primarily because of Fermi contact interactions with the proton and deuteron nuclei. Analysis of these hyperfine multiplets yields values of the Fermi contact hyperfine constants for the lower and upper states in each vibration-rotation transition. These values show that in υ=17 the electron distribution is essentially symmetric, but in υ=21 it becomes increasingly asymmetric as N increases. The proton Fermi contact hyperfine constant is close to 715 MHz in υ=17, but decreases to only 53 MHz in 21,3. Correspondingly the deuteron hyperfine constant increases from 112 MHz in υ=17 to 213 MHz in 21, 3, which is only slightly less than the free deuterium atom value of 218 MHz. These results demonstrate that in 21, 3 the electron is virtually localized at the deuteron, so that the molecule is perhaps best regarded as a long-range H+…D Langevin complex." @default.
- W2316912673 created "2016-06-24" @default.
- W2316912673 creator A5006946156 @default.
- W2316912673 creator A5064869546 @default.
- W2316912673 creator A5074392032 @default.
- W2316912673 date "1988-08-10" @default.
- W2316912673 modified "2023-09-26" @default.
- W2316912673 title "Vibration-rotation spectroscopy of the HD<sup>+</sup>ion near the dissociation limit" @default.
- W2316912673 cites W153370504 @default.
- W2316912673 cites W1972905169 @default.
- W2316912673 cites W1980309338 @default.
- W2316912673 cites W1998584676 @default.
- W2316912673 cites W2002249213 @default.
- W2316912673 cites W2013671089 @default.
- W2316912673 cites W2022272567 @default.
- W2316912673 cites W2026219928 @default.
- W2316912673 cites W2026545896 @default.
- W2316912673 cites W2032850246 @default.
- W2316912673 cites W2037354296 @default.
- W2316912673 cites W2056415105 @default.
- W2316912673 cites W2076114957 @default.
- W2316912673 cites W2085290063 @default.
- W2316912673 cites W2088478187 @default.
- W2316912673 cites W2092889115 @default.
- W2316912673 cites W2253178264 @default.
- W2316912673 cites W2327922417 @default.
- W2316912673 cites W2330067712 @default.
- W2316912673 cites W3115566965 @default.
- W2316912673 doi "https://doi.org/10.1080/00268978800100653" @default.
- W2316912673 hasPublicationYear "1988" @default.
- W2316912673 type Work @default.
- W2316912673 sameAs 2316912673 @default.
- W2316912673 citedByCount "20" @default.
- W2316912673 countsByYear W23169126732013 @default.
- W2316912673 countsByYear W23169126732014 @default.
- W2316912673 countsByYear W23169126732016 @default.
- W2316912673 crossrefType "journal-article" @default.
- W2316912673 hasAuthorship W2316912673A5006946156 @default.
- W2316912673 hasAuthorship W2316912673A5064869546 @default.
- W2316912673 hasAuthorship W2316912673A5074392032 @default.
- W2316912673 hasConcept C108192451 @default.
- W2316912673 hasConcept C121332964 @default.
- W2316912673 hasConcept C131538251 @default.
- W2316912673 hasConcept C145148216 @default.
- W2316912673 hasConcept C178790620 @default.
- W2316912673 hasConcept C184779094 @default.
- W2316912673 hasConcept C185592680 @default.
- W2316912673 hasConcept C54516573 @default.
- W2316912673 hasConcept C58364064 @default.
- W2316912673 hasConcept C62520636 @default.
- W2316912673 hasConceptScore W2316912673C108192451 @default.
- W2316912673 hasConceptScore W2316912673C121332964 @default.
- W2316912673 hasConceptScore W2316912673C131538251 @default.
- W2316912673 hasConceptScore W2316912673C145148216 @default.
- W2316912673 hasConceptScore W2316912673C178790620 @default.
- W2316912673 hasConceptScore W2316912673C184779094 @default.
- W2316912673 hasConceptScore W2316912673C185592680 @default.
- W2316912673 hasConceptScore W2316912673C54516573 @default.
- W2316912673 hasConceptScore W2316912673C58364064 @default.
- W2316912673 hasConceptScore W2316912673C62520636 @default.
- W2316912673 hasIssue "5" @default.
- W2316912673 hasLocation W23169126731 @default.
- W2316912673 hasOpenAccess W2316912673 @default.
- W2316912673 hasPrimaryLocation W23169126731 @default.
- W2316912673 hasRelatedWork W1620141299 @default.
- W2316912673 hasRelatedWork W1964716477 @default.
- W2316912673 hasRelatedWork W1987915577 @default.
- W2316912673 hasRelatedWork W1993457891 @default.
- W2316912673 hasRelatedWork W2009685130 @default.
- W2316912673 hasRelatedWork W2025023318 @default.
- W2316912673 hasRelatedWork W2072584024 @default.
- W2316912673 hasRelatedWork W2090207387 @default.
- W2316912673 hasRelatedWork W2586596202 @default.
- W2316912673 hasRelatedWork W2589573261 @default.
- W2316912673 hasVolume "64" @default.
- W2316912673 isParatext "false" @default.
- W2316912673 isRetracted "false" @default.
- W2316912673 magId "2316912673" @default.
- W2316912673 workType "article" @default.