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• W2316942384 abstract "In this work, gel/glass/cage effects using the Achillias and Kiparissides (AK) model has been incorporated in the analytical solution (AS) obtained in our previous work. The AK model is based on the Chiu, Carratt, and Soong (CCS) model and free volume theory. The results of AS matched quite well with the numerical solutions as well as with the experimental data for methyl methacrylate (MMA). Various variables like termination kinetic coefficient, initiator efficiency, macroradicals concentration profile matched with the established published results. The work clearly demonstrates that AS is sufficiently flexible to accommodate gel/glass/cage effects explicitly although it was not primarily derived for these conditions. This extends the practical usage of AS for the whole range of conversion under isothermal conditions." @default.
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• W2316942384 date "2014-10-27" @default.
• W2316942384 modified "2023-10-13" @default.
• W2316942384 title "Analytical Solution of Free Radical Polymerization: Applications- Implementing Gel Effect Using AK Model" @default.
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• W2316942384 doi "https://doi.org/10.1021/ma501413m" @default.
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