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- W2316954273 abstract "In this Article, we investigated the dielectric properties of B-site Ga-doped K0.5Na0.5NbO3 (KNN) in air using AC impedance spectroscopy from room temperature to about 800 °C. Powder X-ray diffraction (PXRD) studies showed the formation of perovskite-type structure with orthorhombic symmetry, √2ap × 4ap × √2ap (where ap is perovskite-type lattice constant) for x = 0.01, 0.1, and 0.13 members of Na0.5K0.5Nb1−xGaxO3. The PXRD result is similar to the parent KNN structure. AC impedance results showed mainly bulk contribution over the frequency range of 0.1 Hz to 1 MHz for the x = 0.01 member, while bulk and grain-boundary contributions were present for x > 0.01 in the same frequency range. Scanning electron microscopy was used to study the effect of microstructure change for Ga3+ substitution in KNN. The inclusion of Ga3+ in KNN showed a significant change in the microstructure. The dielectric properties of Na0.5K0.5Nb1−xGaxO3 were enhanced by increasing the Ga3+ content; among the compounds studied, the x = 0.1 member exhibited the highest dielectric constant and lowest dielectric loss at 1 MHz over the temperature range studied. All of the Na0.5K0.5Nb1−xGaxO3 materials had a maximum dielectric constant at around 420 °C, which is consistent with other KNN ceramics reported in the literature and can be attributed to the Curie temperature. A small peak in the dielectric constant at around 220 °C was due to a structural phase transition." @default.
- W2316954273 created "2016-06-24" @default.
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- W2316954273 date "2009-02-24" @default.
- W2316954273 modified "2023-10-16" @default.
- W2316954273 title "Dielectric Properties of Ga-Doped Na<sub>0.5</sub>K<sub>0.5</sub>NbO<sub>3</sub>" @default.
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- W2316954273 doi "https://doi.org/10.1021/jp809905u" @default.
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