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• W2316956978 abstract "Dissociation of ethanethiol and the formation of Au-adatom-diethylthiolate rows on the Au(111) surface were investigated using scanning tunneling microscopy (STM) at low temperature. Ethanethiol molecules physisorb on Au(111) at 120 K by sequentially occupation of the elbow site, the fcc domain before covering the whole surface with a semiliquid layer without long-range order. Scanning the physisorbed layer with a sample bias higher than +1.2 V leads to dissociation via cleaving the H–S bond. One of the dissociation products, ethylthiolate, forms a double-row structure with the rows aligned in one of the ⟨112̅⟩ directions. These double rows arise from the Au-adatom-dithiolate species: CH3CH2S–Au–SCH2CH3." @default.
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• W2316956978 date "2012-07-18" @default.
• W2316956978 modified "2023-10-18" @default.
• W2316956978 title "Adsorption and Electron-Induced Dissociation of Ethanethiol on Au(111)" @default.
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• W2316956978 doi "https://doi.org/10.1021/la301779m" @default.
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