Matches in SemOpenAlex for { <https://semopenalex.org/work/W2316961472> ?p ?o ?g. }
Showing items 1 to 63 of
63
with 100 items per page.
- W2316961472 endingPage "516" @default.
- W2316961472 startingPage "510" @default.
- W2316961472 abstract "Authors investigated the hydrocarbons which were generated in the process of catalytic reduction of fatty ester to obtain higher alcohol under high pressure H2.Methyl palmitate, cetyl alcohol and cetyl acetate were treated under high pressure H2 (initial pressure 100200atm.) in the existence of various kinds of catalysts, such as Cu-Cr-O, Zn-Al-O, Zn-Cr-O, Fe-Al-O, Fe-Cu-Al-O, Fe2O3, reduced Fe, ZnO, Al2O3, CuO, Cr2O3 and Raney Ni (W-7).The amount and the constituent of generated hydrocarbon depended on catalyst used and reaction temperature. In the case of reduced Fe and metal oxides, the generation of hydrocarbon having 16 carbons, considered to be produced by dehydration of the alcohol, was preferential to the generation of hydrocarbon having 15 carbons, considered to be produced by elimination of methylol group from alcohol.The order of its priority was as follows, Fe-Cu-Al-O>ZnO, CuO, reduced Fe, Al2O3>Zn-Cr-O, Fe-Al-O>Cr2O3, Fe2O3>Cu-Cr-O.In the case of Cu-Cr-O catalyst, there was no appreciable difference in the amount of both hydrocarbons generated.On the other hand, in the case of Raney Ni the generation of C15 hydrocarbon was predominant, and the generation of C16 hydrocarbon was almost the same as those of C14 and less carbon number hydrocarbons.In spite of the presence of high pressure H2, the content of olefin in hydrocarbon formed increased in such order as Fe-Al-O<Zn-Al-O<Zn-Cr-O<Cr2O3<ZnO<Al2O3<Fe2O3.At the same reaction temperature, about 300°C, the ease of generation of hydrocarbon was as follows, Raney Ni>Cu-Cr-O>Fe-Cu-Al-O>reduced Fe>Fe-Al-O>Zn-Al-O, ZnO>Cr2O3>CuO>Fe2O3, Zn-Cr-O, Al2O3.The optimum reaction temperature to produce higher alcohol was different by each of the catalyst and the amount of hydrocarbon formed increased in such order as Fe-Al-O>Zn-Al-O>Zn-Cr-O>Cu-Cr-O." @default.
- W2316961472 created "2016-06-24" @default.
- W2316961472 creator A5040474648 @default.
- W2316961472 creator A5049923362 @default.
- W2316961472 creator A5084250046 @default.
- W2316961472 date "1965-01-01" @default.
- W2316961472 modified "2023-10-16" @default.
- W2316961472 title "On the Hydrocarbons Generated in Catalytic Reduction of Fatty Ester" @default.
- W2316961472 doi "https://doi.org/10.5650/jos1956.14.510" @default.
- W2316961472 hasPublicationYear "1965" @default.
- W2316961472 type Work @default.
- W2316961472 sameAs 2316961472 @default.
- W2316961472 citedByCount "1" @default.
- W2316961472 crossrefType "journal-article" @default.
- W2316961472 hasAuthorship W2316961472A5040474648 @default.
- W2316961472 hasAuthorship W2316961472A5049923362 @default.
- W2316961472 hasAuthorship W2316961472A5084250046 @default.
- W2316961472 hasBestOaLocation W23169614721 @default.
- W2316961472 hasConcept C104779481 @default.
- W2316961472 hasConcept C140205800 @default.
- W2316961472 hasConcept C159985019 @default.
- W2316961472 hasConcept C161790260 @default.
- W2316961472 hasConcept C178790620 @default.
- W2316961472 hasConcept C179104552 @default.
- W2316961472 hasConcept C185592680 @default.
- W2316961472 hasConcept C192562407 @default.
- W2316961472 hasConcept C2777207669 @default.
- W2316961472 hasConcept C2781066024 @default.
- W2316961472 hasConcept C51886252 @default.
- W2316961472 hasConcept C544153396 @default.
- W2316961472 hasConceptScore W2316961472C104779481 @default.
- W2316961472 hasConceptScore W2316961472C140205800 @default.
- W2316961472 hasConceptScore W2316961472C159985019 @default.
- W2316961472 hasConceptScore W2316961472C161790260 @default.
- W2316961472 hasConceptScore W2316961472C178790620 @default.
- W2316961472 hasConceptScore W2316961472C179104552 @default.
- W2316961472 hasConceptScore W2316961472C185592680 @default.
- W2316961472 hasConceptScore W2316961472C192562407 @default.
- W2316961472 hasConceptScore W2316961472C2777207669 @default.
- W2316961472 hasConceptScore W2316961472C2781066024 @default.
- W2316961472 hasConceptScore W2316961472C51886252 @default.
- W2316961472 hasConceptScore W2316961472C544153396 @default.
- W2316961472 hasIssue "9" @default.
- W2316961472 hasLocation W23169614721 @default.
- W2316961472 hasOpenAccess W2316961472 @default.
- W2316961472 hasPrimaryLocation W23169614721 @default.
- W2316961472 hasRelatedWork W143147499 @default.
- W2316961472 hasRelatedWork W1599491654 @default.
- W2316961472 hasRelatedWork W1964022167 @default.
- W2316961472 hasRelatedWork W202311849 @default.
- W2316961472 hasRelatedWork W2044048544 @default.
- W2316961472 hasRelatedWork W211624929 @default.
- W2316961472 hasRelatedWork W2147427301 @default.
- W2316961472 hasRelatedWork W2161135774 @default.
- W2316961472 hasRelatedWork W2381214870 @default.
- W2316961472 hasRelatedWork W35455059 @default.
- W2316961472 hasVolume "14" @default.
- W2316961472 isParatext "false" @default.
- W2316961472 isRetracted "false" @default.
- W2316961472 magId "2316961472" @default.
- W2316961472 workType "article" @default.