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- W2316962627 abstract "Three isomorphic decanuclear heterometallic 3d–4f Ln2Cu8 clusters, formulated as [Ln2Cu8(μ2-OH)2(μ3-OH)2(ClO4)2(HTMHSA)4(H2O)10]·15H2O (Ln = La (1, La2Cu8); Ln = Gd (2, Gd2Cu8); Ln = Dy (3, Dy2Cu8), H5TMHSA = 3-[N-tris(hydroxymethyl)methylamino]-2-hydroxyprop-anesulfonic acid), were obtained through the reaction of H5TMHSA, Ln(ClO4)3, and Cu(NO3)2·3H2O. The present three Ln2Cu8 compounds are rare examples of alkylsulfonate-based polynuclear 3d–4f clusters. Magnetic studies indicate that the cluster La2Cu8 exhibits antiferromagnetic behavior, Gd2Cu8 displays ferromagnetic behavior and a large magnetocaloric effect at low temperature, while Dy2Cu8 shows slow magnetic relaxation." @default.
- W2316962627 created "2016-06-24" @default.
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- W2316962627 date "2013-05-20" @default.
- W2316962627 modified "2023-09-24" @default.
- W2316962627 title "Synthesis, Structures, and Magnetic Properties of Three Decanuclear Ln<sub>2</sub>Cu<sub>8</sub> Clusters of Alkylsulfonate" @default.
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- W2316962627 doi "https://doi.org/10.1021/cg400206s" @default.
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