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- W2316971750 abstract "Five representatives of a novel class of 1,3-bidentate and exclusively centrostereogenic ferrocenyldiphosphane ligands were prepared from ferrocene in a five-step sequence. The ligands were tested in rhodium-mediated asymmetric hydrogenations of two alkenes (methyl acetamidocinnamate and dimethyl itaconate) and delivered high product enantioselectivities of up to 96% ee. The coordination behavior of one ligand in its square-planar palladium dichloride complex was studied by X-ray diffraction, and the R absolute configuration was determined from the X-ray anomalous dispersion effects." @default.
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- W2316971750 date "2010-11-08" @default.
- W2316971750 modified "2023-10-11" @default.
- W2316971750 title "Synthesis of Exclusively Centrostereogenic 1,3-Bidentate Ferrocenyldiphosphane Ligands and Their Use in Enantioselective Hydrogenations" @default.
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- W2316971750 doi "https://doi.org/10.1021/om100830m" @default.
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