Matches in SemOpenAlex for { <https://semopenalex.org/work/W2316994600> ?p ?o ?g. }
- W2316994600 endingPage "7495" @default.
- W2316994600 startingPage "7484" @default.
- W2316994600 abstract "The microstructure and rheological properties of micellar solutions of Pluronic block copolymers (PEOx–PPOy–PEOx) in deuterated ethylammonium nitrate (dEAN, a protic ionic liquid) are studied by small- and ultrasmall-angle neutron scattering (SANS and USANS), fluorescence microscopy, and shear rheology. A homologous series of three Pluronics with similar PPO block length (F127 (PEO106–PPO70–PEO106), P123 (PEO20–PPO70–PEO20), and L121 (PEO5–PPO70–PEO5)) are examined to explore the effect of the relative balance of solvophilic to solvophobic block size on the self-assembled microstructure. Both F127 and P123 form spherical micelles in dEAN that assemble into face-centered and body-centered cubic supramolecular crystals, respectively, upon increasing concentration or temperature. The transition from disordered to crystalline (ordered) structures manifests as a sol–gel rheological transition. A richer phase diagram is observed in the L121/dEAN system: due to its low solvophilicity in dEAN, L121 self-assembles into structures with low curvatures, namely, vesicles in the dilute regime, elongated (wormlike) micelles at intermediate concentrations and low temperatures, a nematic phase in concentrated solutions, and multilamellar phases at high temperatures. Highly viscoelastic solutions are created by the self-assembly of entangled L121 wormlike micelles. Structural length scales of the three Pluronic/dEAN systems in the various mesophases are determined from SANS and USANS." @default.
- W2316994600 created "2016-06-24" @default.
- W2316994600 creator A5019634788 @default.
- W2316994600 creator A5033178403 @default.
- W2316994600 creator A5077644182 @default.
- W2316994600 creator A5078306404 @default.
- W2316994600 date "2014-10-22" @default.
- W2316994600 modified "2023-09-28" @default.
- W2316994600 title "Triblock Copolymer Self-Assembly in Ionic Liquids: Effect of PEO Block Length on the Self-Assembly of PEO–PPO–PEO in Ethylammonium Nitrate" @default.
- W2316994600 cites W1579170559 @default.
- W2316994600 cites W1966124174 @default.
- W2316994600 cites W1969169842 @default.
- W2316994600 cites W1972846853 @default.
- W2316994600 cites W1974915511 @default.
- W2316994600 cites W1978199313 @default.
- W2316994600 cites W1984130749 @default.
- W2316994600 cites W1985974368 @default.
- W2316994600 cites W1990178568 @default.
- W2316994600 cites W1991721274 @default.
- W2316994600 cites W2002158695 @default.
- W2316994600 cites W2002861266 @default.
- W2316994600 cites W2008052341 @default.
- W2316994600 cites W2015336984 @default.
- W2316994600 cites W2019916528 @default.
- W2316994600 cites W2020959202 @default.
- W2316994600 cites W2028344502 @default.
- W2316994600 cites W2034382660 @default.
- W2316994600 cites W2035856926 @default.
- W2316994600 cites W2037840068 @default.
- W2316994600 cites W2040426941 @default.
- W2316994600 cites W2044585912 @default.
- W2316994600 cites W2046382342 @default.
- W2316994600 cites W2052458929 @default.
- W2316994600 cites W2055089331 @default.
- W2316994600 cites W2059935370 @default.
- W2316994600 cites W2061196290 @default.
- W2316994600 cites W2062633203 @default.
- W2316994600 cites W2068048034 @default.
- W2316994600 cites W2070180694 @default.
- W2316994600 cites W2070442888 @default.
- W2316994600 cites W2074339093 @default.
- W2316994600 cites W2076922484 @default.
- W2316994600 cites W2079745709 @default.
- W2316994600 cites W2083309450 @default.
- W2316994600 cites W2087835260 @default.
- W2316994600 cites W2088341412 @default.
- W2316994600 cites W2089439093 @default.
- W2316994600 cites W2090610633 @default.
- W2316994600 cites W2104717900 @default.
- W2316994600 cites W2107974138 @default.
- W2316994600 cites W2114443386 @default.
- W2316994600 cites W2122676372 @default.
- W2316994600 cites W2139055039 @default.
- W2316994600 cites W2148447332 @default.
- W2316994600 cites W2164293345 @default.
- W2316994600 cites W2323823316 @default.
- W2316994600 cites W2325518545 @default.
- W2316994600 cites W2329920817 @default.
- W2316994600 cites W2333737839 @default.
- W2316994600 cites W4248104288 @default.
- W2316994600 cites W4248403368 @default.
- W2316994600 cites W4323285541 @default.
- W2316994600 doi "https://doi.org/10.1021/ma501238w" @default.
- W2316994600 hasPublicationYear "2014" @default.
- W2316994600 type Work @default.
- W2316994600 sameAs 2316994600 @default.
- W2316994600 citedByCount "43" @default.
- W2316994600 countsByYear W23169946002015 @default.
- W2316994600 countsByYear W23169946002016 @default.
- W2316994600 countsByYear W23169946002017 @default.
- W2316994600 countsByYear W23169946002018 @default.
- W2316994600 countsByYear W23169946002019 @default.
- W2316994600 countsByYear W23169946002020 @default.
- W2316994600 countsByYear W23169946002021 @default.
- W2316994600 countsByYear W23169946002022 @default.
- W2316994600 countsByYear W23169946002023 @default.
- W2316994600 crossrefType "journal-article" @default.
- W2316994600 hasAuthorship W2316994600A5019634788 @default.
- W2316994600 hasAuthorship W2316994600A5033178403 @default.
- W2316994600 hasAuthorship W2316994600A5077644182 @default.
- W2316994600 hasAuthorship W2316994600A5078306404 @default.
- W2316994600 hasConcept C101335993 @default.
- W2316994600 hasConcept C104015590 @default.
- W2316994600 hasConcept C11268172 @default.
- W2316994600 hasConcept C115624301 @default.
- W2316994600 hasConcept C120665830 @default.
- W2316994600 hasConcept C121332964 @default.
- W2316994600 hasConcept C127413603 @default.
- W2316994600 hasConcept C131888329 @default.
- W2316994600 hasConcept C13274807 @default.
- W2316994600 hasConcept C132841051 @default.
- W2316994600 hasConcept C147789679 @default.
- W2316994600 hasConcept C154881586 @default.
- W2316994600 hasConcept C15920480 @default.
- W2316994600 hasConcept C159985019 @default.
- W2316994600 hasConcept C161790260 @default.
- W2316994600 hasConcept C166361863 @default.
- W2316994600 hasConcept C171250308 @default.