Matches in SemOpenAlex for { <https://semopenalex.org/work/W2317015462> ?p ?o ?g. }
- W2317015462 endingPage "10368" @default.
- W2317015462 startingPage "10360" @default.
- W2317015462 abstract "A series of diformylbenzophenones were generated by sequentially reacting protected bromobenzaldehydes with n-butyllithium and ethyl N,N-dimethylcarbamate. The acetal protective groups were cleaved with refluxing formic acid. Vilsmeier–Haack formylation of 2,2′,4,4′-tetramethoxybenzophenone also afforded a related dialdehyde. MacDonald “2 + 2” condensation of three benzophenone dialdehydes with a dipyrrylmethane gave oxophlorin analogues constructed from two benzene and two pyrrole rings. The free base oxodibenziphlorins were rather unstable in solution, and in most cases these porphyrinoids were isolated as the corresponding trifluoroacetate salts. The spectroscopic properties of 6-oxo-adj-dibenziphlorins are consistent with a nonaromatic ring system. DFT calculations indicated that the macrocycles considerably diverge from planarity, particularly when methoxy substituents are present on the arene rings." @default.
- W2317015462 created "2016-06-24" @default.
- W2317015462 creator A5015411121 @default.
- W2317015462 creator A5066014054 @default.
- W2317015462 creator A5084449121 @default.
- W2317015462 date "2013-10-04" @default.
- W2317015462 modified "2023-10-18" @default.
- W2317015462 title "Dicarbaporphyrinoid Systems. Synthesis of Oxo-<i>adj</i>-dibenziphlorins" @default.
- W2317015462 cites W1968019061 @default.
- W2317015462 cites W1975577323 @default.
- W2317015462 cites W1977792988 @default.
- W2317015462 cites W1981828770 @default.
- W2317015462 cites W1984899017 @default.
- W2317015462 cites W1986479447 @default.
- W2317015462 cites W1989124389 @default.
- W2317015462 cites W1995835241 @default.
- W2317015462 cites W2002392548 @default.
- W2317015462 cites W2004823085 @default.
- W2317015462 cites W2004961741 @default.
- W2317015462 cites W2011781503 @default.
- W2317015462 cites W2012523935 @default.
- W2317015462 cites W2018498033 @default.
- W2317015462 cites W2019791034 @default.
- W2317015462 cites W2020779380 @default.
- W2317015462 cites W2025844140 @default.
- W2317015462 cites W2030417455 @default.
- W2317015462 cites W2030971462 @default.
- W2317015462 cites W2034911069 @default.
- W2317015462 cites W2037013279 @default.
- W2317015462 cites W2042239958 @default.
- W2317015462 cites W2050751359 @default.
- W2317015462 cites W2056545556 @default.
- W2317015462 cites W2068141899 @default.
- W2317015462 cites W2077732642 @default.
- W2317015462 cites W2085536493 @default.
- W2317015462 cites W2107145271 @default.
- W2317015462 cites W2108402724 @default.
- W2317015462 cites W2130435164 @default.
- W2317015462 cites W2153968545 @default.
- W2317015462 cites W2159882285 @default.
- W2317015462 cites W2313645014 @default.
- W2317015462 cites W4237387472 @default.
- W2317015462 doi "https://doi.org/10.1021/jo401756q" @default.
- W2317015462 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24063344" @default.
- W2317015462 hasPublicationYear "2013" @default.
- W2317015462 type Work @default.
- W2317015462 sameAs 2317015462 @default.
- W2317015462 citedByCount "10" @default.
- W2317015462 countsByYear W23170154622014 @default.
- W2317015462 countsByYear W23170154622015 @default.
- W2317015462 countsByYear W23170154622016 @default.
- W2317015462 countsByYear W23170154622018 @default.
- W2317015462 countsByYear W23170154622020 @default.
- W2317015462 countsByYear W23170154622023 @default.
- W2317015462 crossrefType "journal-article" @default.
- W2317015462 hasAuthorship W2317015462A5015411121 @default.
- W2317015462 hasAuthorship W2317015462A5066014054 @default.
- W2317015462 hasAuthorship W2317015462A5084449121 @default.
- W2317015462 hasConcept C121332964 @default.
- W2317015462 hasConcept C155647269 @default.
- W2317015462 hasConcept C161790260 @default.
- W2317015462 hasConcept C178790620 @default.
- W2317015462 hasConcept C185592680 @default.
- W2317015462 hasConcept C200093464 @default.
- W2317015462 hasConcept C2777379063 @default.
- W2317015462 hasConcept C2777691172 @default.
- W2317015462 hasConcept C2777731525 @default.
- W2317015462 hasConcept C2778279444 @default.
- W2317015462 hasConcept C2778651986 @default.
- W2317015462 hasConcept C2779155132 @default.
- W2317015462 hasConcept C2779400197 @default.
- W2317015462 hasConcept C2780378348 @default.
- W2317015462 hasConcept C2780450521 @default.
- W2317015462 hasConcept C71240020 @default.
- W2317015462 hasConcept C97355855 @default.
- W2317015462 hasConceptScore W2317015462C121332964 @default.
- W2317015462 hasConceptScore W2317015462C155647269 @default.
- W2317015462 hasConceptScore W2317015462C161790260 @default.
- W2317015462 hasConceptScore W2317015462C178790620 @default.
- W2317015462 hasConceptScore W2317015462C185592680 @default.
- W2317015462 hasConceptScore W2317015462C200093464 @default.
- W2317015462 hasConceptScore W2317015462C2777379063 @default.
- W2317015462 hasConceptScore W2317015462C2777691172 @default.
- W2317015462 hasConceptScore W2317015462C2777731525 @default.
- W2317015462 hasConceptScore W2317015462C2778279444 @default.
- W2317015462 hasConceptScore W2317015462C2778651986 @default.
- W2317015462 hasConceptScore W2317015462C2779155132 @default.
- W2317015462 hasConceptScore W2317015462C2779400197 @default.
- W2317015462 hasConceptScore W2317015462C2780378348 @default.
- W2317015462 hasConceptScore W2317015462C2780450521 @default.
- W2317015462 hasConceptScore W2317015462C71240020 @default.
- W2317015462 hasConceptScore W2317015462C97355855 @default.
- W2317015462 hasIssue "20" @default.
- W2317015462 hasLocation W23170154621 @default.
- W2317015462 hasLocation W23170154622 @default.
- W2317015462 hasOpenAccess W2317015462 @default.
- W2317015462 hasPrimaryLocation W23170154621 @default.
- W2317015462 hasRelatedWork W1975723851 @default.