Matches in SemOpenAlex for { <https://semopenalex.org/work/W2317057241> ?p ?o ?g. }
- W2317057241 endingPage "15" @default.
- W2317057241 startingPage "12" @default.
- W2317057241 abstract "Unusual nucleophilic cobalt fluorocarbene complexes ([CoI]═CFR; R = F, CF3) are described. Only a handful of fluorocarbenes of first-row transition metals have been reported, and these have exhibited electrophilic reactivity at the metal–carbene bonds. The title compounds are the first persistent/isolable cobalt fluorocarbenes and also rare examples of metal fluorocarbenes with relatively nucleophilic M═C bonds (vs other metal fluorocarbene complexes), demonstrated by their reactions with H+ and Me+ and their unusual stability toward water. X-ray crystal structures reveal the shortest terminal cobalt–carbene bonds reported to date, and DFT studies provide details into the nature of these bonds." @default.
- W2317057241 created "2016-06-24" @default.
- W2317057241 creator A5011902697 @default.
- W2317057241 creator A5026611636 @default.
- W2317057241 creator A5027944192 @default.
- W2317057241 creator A5029196919 @default.
- W2317057241 creator A5079273246 @default.
- W2317057241 date "2012-12-24" @default.
- W2317057241 modified "2023-10-16" @default.
- W2317057241 title "Cobalt Fluorocarbene Complexes" @default.
- W2317057241 cites W1650728208 @default.
- W2317057241 cites W1965451570 @default.
- W2317057241 cites W1966101188 @default.
- W2317057241 cites W1968392598 @default.
- W2317057241 cites W1971441007 @default.
- W2317057241 cites W1973498644 @default.
- W2317057241 cites W1973776351 @default.
- W2317057241 cites W1981368803 @default.
- W2317057241 cites W1983744652 @default.
- W2317057241 cites W1987942641 @default.
- W2317057241 cites W1988932237 @default.
- W2317057241 cites W1989177510 @default.
- W2317057241 cites W1990878104 @default.
- W2317057241 cites W1993383767 @default.
- W2317057241 cites W2000615515 @default.
- W2317057241 cites W2000872531 @default.
- W2317057241 cites W2005004725 @default.
- W2317057241 cites W2013963010 @default.
- W2317057241 cites W2025356565 @default.
- W2317057241 cites W2030340979 @default.
- W2317057241 cites W2037628795 @default.
- W2317057241 cites W2038493270 @default.
- W2317057241 cites W2039294840 @default.
- W2317057241 cites W2043068345 @default.
- W2317057241 cites W2044245624 @default.
- W2317057241 cites W2048366320 @default.
- W2317057241 cites W2057359850 @default.
- W2317057241 cites W2057370118 @default.
- W2317057241 cites W2058210956 @default.
- W2317057241 cites W2058978512 @default.
- W2317057241 cites W2064526138 @default.
- W2317057241 cites W2068103829 @default.
- W2317057241 cites W2069773843 @default.
- W2317057241 cites W2070125875 @default.
- W2317057241 cites W2087126997 @default.
- W2317057241 cites W2088134782 @default.
- W2317057241 cites W2088197653 @default.
- W2317057241 cites W2088607593 @default.
- W2317057241 cites W2094302071 @default.
- W2317057241 cites W2111663241 @default.
- W2317057241 cites W2126630326 @default.
- W2317057241 cites W2150484258 @default.
- W2317057241 cites W2157298837 @default.
- W2317057241 cites W2329275632 @default.
- W2317057241 cites W2592390614 @default.
- W2317057241 cites W2952848839 @default.
- W2317057241 cites W2953041988 @default.
- W2317057241 cites W2078689059 @default.
- W2317057241 doi "https://doi.org/10.1021/om3010959" @default.
- W2317057241 hasPublicationYear "2012" @default.
- W2317057241 type Work @default.
- W2317057241 sameAs 2317057241 @default.
- W2317057241 citedByCount "55" @default.
- W2317057241 countsByYear W23170572412013 @default.
- W2317057241 countsByYear W23170572412014 @default.
- W2317057241 countsByYear W23170572412015 @default.
- W2317057241 countsByYear W23170572412016 @default.
- W2317057241 countsByYear W23170572412017 @default.
- W2317057241 countsByYear W23170572412018 @default.
- W2317057241 countsByYear W23170572412019 @default.
- W2317057241 countsByYear W23170572412020 @default.
- W2317057241 countsByYear W23170572412021 @default.
- W2317057241 countsByYear W23170572412022 @default.
- W2317057241 countsByYear W23170572412023 @default.
- W2317057241 crossrefType "journal-article" @default.
- W2317057241 hasAuthorship W2317057241A5011902697 @default.
- W2317057241 hasAuthorship W2317057241A5026611636 @default.
- W2317057241 hasAuthorship W2317057241A5027944192 @default.
- W2317057241 hasAuthorship W2317057241A5029196919 @default.
- W2317057241 hasAuthorship W2317057241A5079273246 @default.
- W2317057241 hasConcept C106773901 @default.
- W2317057241 hasConcept C142724271 @default.
- W2317057241 hasConcept C155647269 @default.
- W2317057241 hasConcept C161790260 @default.
- W2317057241 hasConcept C178790620 @default.
- W2317057241 hasConcept C178907741 @default.
- W2317057241 hasConcept C179104552 @default.
- W2317057241 hasConcept C185592680 @default.
- W2317057241 hasConcept C204787440 @default.
- W2317057241 hasConcept C2776910235 @default.
- W2317057241 hasConcept C2777164566 @default.
- W2317057241 hasConcept C50027330 @default.
- W2317057241 hasConcept C515602321 @default.
- W2317057241 hasConcept C544153396 @default.
- W2317057241 hasConcept C71240020 @default.
- W2317057241 hasConcept C71924100 @default.
- W2317057241 hasConcept C8010536 @default.
- W2317057241 hasConceptScore W2317057241C106773901 @default.