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- W2317074945 abstract "Hydrothermal reactions of VOSO4 center dot 3H(2)O, CdAc2 center dot 2H(2)O, NiCl2 center dot 6H(2)O, H3PO4, and H2O yield the first example of trimetallic phosphate materials, [Ni(H2O)(4)]Cd(VO)(PO4)(2) 1. The single-crystal X-ray diffraction shows that its structure consists of Cd/V/O binary metal oxide lamellas decorated by PO4 tetrahedra, which are further pillared by NiO2(H2O)4 octahedra to generate a neutral 3-D framework containing two intercrossing 8-MR channels where. the coordinated water molecules protrude into. Thermal and magnetic behaviors of this material were also measured. Crystal data: CdNiVP2O13H8, orthorhombic Ibca (No.73), a = 7.1307(2) angstrom, b = 18.6248(3) angstrom, c = 14.8046(2) angstrom, V = 1966.17(7) angstrom(3), Z = 8. (c) 2007 Elsevier Inc. All rights reserved." @default.
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- W2317074945 date "2007-06-01" @default.
- W2317074945 modified "2023-09-24" @default.
- W2317074945 title "Synthesis, structure, and properties of the first trimetallic phosphate [Ni(H2O)4]Cd(VO)(PO4)2 with neutral 3-D pillared-layer framework" @default.
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- W2317074945 doi "https://doi.org/10.1016/j.jssc.2007.04.019" @default.
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