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• W2317107866 abstract "A novel Ru(II) complex-based phosphorescent probe Rubpy-1 was designed and synthesized conveniently by incorporating of chemodosimeter into the luminophor, which exhibits good water solubility, longer excitation wavelength, and rapid turn-on phosphorescent response only toward Hg(2+) in aqueous system under physiological pH. The spectral response mechanism and Hg(2+)-promoted structure change of the chemodosimeter were analyzed in detail by theoretical calculations and electrospray ionization mass spectrometry. When time-resolved photoluminescence techniques were used, the Rubpy-1 could eliminate effectively the signal interference from the short-lived background fluorescence in complicated media, accompanied by the significant improvement of the signal-to-noise ratio and the accuracy of the detection. Furthermore, Rubpy-1 showed low cytotoxicity and excellent membrane permeability toward living cells, which was successfully applied to monitor intracellular Hg(2+) effectively by confocal luminescence imaging." @default.
• W2317107866 created "2016-06-24" @default.
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• W2317107866 date "2015-02-10" @default.
• W2317107866 modified "2023-10-17" @default.
• W2317107866 title "Exploitation and Application of a Highly Sensitive Ru(II) Complex-Based Phosphorescent Chemodosimeter for Hg²⁺ in Aqueous Solutions and Living Cells" @default.
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• W2317107866 doi "https://doi.org/10.1021/am508484q" @default.
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• W2317107866 hasPublicationYear "2015" @default.
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