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- W2317143957 abstract "Abstract The addition of La 2 O 3 to an aniline polymerizing system to promote the formation of polyaniline nanofibers (PANI-La 2 O 3 ) is herein demonstrated. The fiberization rate is significantly increased by the inducing of La 2 O 3 . Only trace amounts of lanthanum advantageously remain in the product, which therefore negligibly influence the electrochemical characteristics of the resulting polyaniline fibers. Research for the electrochemical reaction kinetics of PANI-La 2 O 3 nanofiber indicates that the redox rate of polyaniline between leucoemeraldine and emeraldine is controlled by electron transfer and proton (H + ) diffusion. The standard rate constants of the redox and the diffusion coefficients of H + are measured at 20 ºC. Cyclic voltammetric (CV) results indicate that PANI-La 2 O 3 nanofibers are resistant against electrochemical degradation. Moreover, the modification of Pt electrode with PANI-La 2 O 3 nanofibers promotes the efficiency of methanol electro-oxidation." @default.
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- W2317143957 date "2013-01-01" @default.
- W2317143957 modified "2023-09-23" @default.
- W2317143957 title "Characteristics and Electrochemical Reaction Kinetics of Polyaniline Nanofibers as a Promoter of Pt Electrode for Methanol Electrocatalytic Oxidation" @default.
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- W2317143957 doi "https://doi.org/10.1524/zpch.2013.0252" @default.
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