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- W2317146581 startingPage "921" @default.
- W2317146581 abstract "4 種類のペルフルオロアルカン酸塩同族体, CnF2n+1COOLi (n=5～10), CnF2n+1COONa (n=5～8), CnF2n+1COOMe4N (n=5～10), CnF2n+1COOEt4N (n=4～10) の水中における臨界ミセル濃度 (cmc) を 25℃で測定し, 結果をlog cmc=A+Bnの形に表した。B値は, -0.445～-0.463となり, cmcはペルフルオロアルキル鎖のCF2基当たり2.8～2.9ずつ減少することを示した。cmcに対する対イオンの効果を C7F15COO-M+ (M=Li, Na, K) について35℃で調べた。cmcはLi>Na>Kの順に減少する事が見いだされた。水中におけるCnF2n+1COOMe4N (n=1～6) の極限部分モル体積 (V0) を25℃で測定した。V0値は炭素数と共に増加し, CF2基当たりの増加は平均して23.7cm3・mol-1であった。" @default.
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- W2317146581 date "1997-01-01" @default.
- W2317146581 modified "2023-10-16" @default.
- W2317146581 title "Critical Micelle Concentrations and Partial Molar Volumes for Perfluoroalkanoates Salts in Aqueous Solutions." @default.
- W2317146581 doi "https://doi.org/10.5650/jos1996.46.921" @default.
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