Matches in SemOpenAlex for { <https://semopenalex.org/work/W2317150512> ?p ?o ?g. }
- W2317150512 endingPage "1385" @default.
- W2317150512 startingPage "1381" @default.
- W2317150512 abstract "To tailor the catalytic activities of metal catalysts at will to achieve efficient conversion in chemical processes remains a challenge, particularly for noble metals, such as Pt. We demonstrate herein that encapsulation within the carbon nanotube (CNT) channels with a diameter of 1.0–1.5 nm not only allows restriction of the size of Pt nanoclusters around 1.0 nm but also enables modulating of the Pt species at the active reduced states through host–guest interaction. The encapsulated Pt is protected from oxygen under reaction conditions in toluene oxidation up to 200 °C, as unveiled by in situ X-ray absorption spectroscopy and density functional theory calculations. As a result, the encapsulated Pt clusters deliver a remarkably higher activity and stability than the clusters located on the open surfaces of the CNT exterior walls and carbon black support, although the latter are much more accessible to reactants. This characteristic of the CNT channels can be explored to tune the properties of other metal catalysts for oxidation reactions." @default.
- W2317150512 created "2016-06-24" @default.
- W2317150512 creator A5004947752 @default.
- W2317150512 creator A5007247441 @default.
- W2317150512 creator A5020434251 @default.
- W2317150512 creator A5045204358 @default.
- W2317150512 creator A5071870257 @default.
- W2317150512 creator A5075748581 @default.
- W2317150512 creator A5082924617 @default.
- W2317150512 date "2015-01-28" @default.
- W2317150512 modified "2023-10-13" @default.
- W2317150512 title "Tailoring the Oxidation Activity of Pt Nanoclusters via Encapsulation" @default.
- W2317150512 cites W1964831190 @default.
- W2317150512 cites W1979757536 @default.
- W2317150512 cites W1984372824 @default.
- W2317150512 cites W1989895933 @default.
- W2317150512 cites W1993207925 @default.
- W2317150512 cites W1997354715 @default.
- W2317150512 cites W2004878979 @default.
- W2317150512 cites W2022486303 @default.
- W2317150512 cites W2024451528 @default.
- W2317150512 cites W2040781985 @default.
- W2317150512 cites W2042116998 @default.
- W2317150512 cites W2046113065 @default.
- W2317150512 cites W2051946021 @default.
- W2317150512 cites W2056941759 @default.
- W2317150512 cites W2060230829 @default.
- W2317150512 cites W2064593245 @default.
- W2317150512 cites W2066443367 @default.
- W2317150512 cites W2069196298 @default.
- W2317150512 cites W2074024937 @default.
- W2317150512 cites W2074717643 @default.
- W2317150512 cites W2077581728 @default.
- W2317150512 cites W2077734974 @default.
- W2317150512 cites W2079342781 @default.
- W2317150512 cites W2080239811 @default.
- W2317150512 cites W2081751323 @default.
- W2317150512 cites W2082770088 @default.
- W2317150512 cites W2088152859 @default.
- W2317150512 cites W2095146078 @default.
- W2317150512 cites W2117015463 @default.
- W2317150512 cites W2127069775 @default.
- W2317150512 cites W2133022989 @default.
- W2317150512 cites W2134716155 @default.
- W2317150512 cites W2138872642 @default.
- W2317150512 cites W2142408964 @default.
- W2317150512 cites W2149265053 @default.
- W2317150512 cites W2159307828 @default.
- W2317150512 cites W2164401501 @default.
- W2317150512 cites W2317322407 @default.
- W2317150512 cites W4211162918 @default.
- W2317150512 cites W4249330882 @default.
- W2317150512 cites W4251158538 @default.
- W2317150512 doi "https://doi.org/10.1021/cs501763k" @default.
- W2317150512 hasPublicationYear "2015" @default.
- W2317150512 type Work @default.
- W2317150512 sameAs 2317150512 @default.
- W2317150512 citedByCount "57" @default.
- W2317150512 countsByYear W23171505122015 @default.
- W2317150512 countsByYear W23171505122016 @default.
- W2317150512 countsByYear W23171505122017 @default.
- W2317150512 countsByYear W23171505122018 @default.
- W2317150512 countsByYear W23171505122019 @default.
- W2317150512 countsByYear W23171505122020 @default.
- W2317150512 countsByYear W23171505122021 @default.
- W2317150512 countsByYear W23171505122022 @default.
- W2317150512 countsByYear W23171505122023 @default.
- W2317150512 crossrefType "journal-article" @default.
- W2317150512 hasAuthorship W2317150512A5004947752 @default.
- W2317150512 hasAuthorship W2317150512A5007247441 @default.
- W2317150512 hasAuthorship W2317150512A5020434251 @default.
- W2317150512 hasAuthorship W2317150512A5045204358 @default.
- W2317150512 hasAuthorship W2317150512A5071870257 @default.
- W2317150512 hasAuthorship W2317150512A5075748581 @default.
- W2317150512 hasAuthorship W2317150512A5082924617 @default.
- W2317150512 hasConcept C119824511 @default.
- W2317150512 hasConcept C121332964 @default.
- W2317150512 hasConcept C127413603 @default.
- W2317150512 hasConcept C147597530 @default.
- W2317150512 hasConcept C152365726 @default.
- W2317150512 hasConcept C161790260 @default.
- W2317150512 hasConcept C171250308 @default.
- W2317150512 hasConcept C175583648 @default.
- W2317150512 hasConcept C178790620 @default.
- W2317150512 hasConcept C185592680 @default.
- W2317150512 hasConcept C186187911 @default.
- W2317150512 hasConcept C191897082 @default.
- W2317150512 hasConcept C192562407 @default.
- W2317150512 hasConcept C2775871042 @default.
- W2317150512 hasConcept C2777619693 @default.
- W2317150512 hasConcept C2778402822 @default.
- W2317150512 hasConcept C42360764 @default.
- W2317150512 hasConcept C513720949 @default.
- W2317150512 hasConcept C544153396 @default.
- W2317150512 hasConcept C62284982 @default.
- W2317150512 hasConcept C62520636 @default.
- W2317150512 hasConceptScore W2317150512C119824511 @default.
- W2317150512 hasConceptScore W2317150512C121332964 @default.