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• W2317187039 abstract "The first examples of heteroleptic bis-N-heterocyclic carbene (NHC) copper(I) complexes and a mixed NHC–phosphine Cu complex are reported. These complexes are easily synthesized from the reaction of [Cu(OH)(NHC)] with various imidazol(idin)ium or phosphonium tetrafluoroborate salts. These cationic heteroleptic bis-NHC Cu complexes are highly active systems for the azide–alkyne cycloaddition leading to the formation of 1,2,3-triazoles. The mechanism of this transformation was investigated, and information gathered suggests that only one NHC remains coordinated to the metal center during catalysis." @default.
• W2317187039 created "2016-06-24" @default.
• W2317187039 creator A5006345917 @default.
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• W2317187039 date "2012-10-31" @default.
• W2317187039 modified "2023-10-13" @default.
• W2317187039 title "Heteroleptic Bis(N-heterocyclic carbene)Copper(I) Complexes: Highly Efficient Systems for the [3+2] Cycloaddition of Azides and Alkynes" @default.
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• W2317187039 doi "https://doi.org/10.1021/om3006195" @default.
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