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• W2317204037 endingPage "10538" @default.
• W2317204037 startingPage "10534" @default.
• W2317204037 abstract "A new series of heterometallic lanthanide(III)−copper(I) coordination polymers Ln2(bdc)2(ina)2(H2O)2Cu·X (Hina = isonicotinic acid; H2bdc = 1,2-benzenedicarboxylic acid; Ln = Eu (1), Sm (2), Nd (3), X = ClO4-; Ln = Nd (4), X = Cl-) have been hydrothermally synthesized in the presence/absence of HClO4. Both compounds are isostructural and contained two distinct units of 2D Ln−bdc layers and linear [Cu(ina)2]-. The linear [Cu(ina)2]- complexes act as pillars and further link the Ln−bdc layers resulting in four heterometallic metal−organic frameworks, which represent the first pillared-layer 3d−4f framework with two distinct types of channels along the b and c axes. The compounds can be specified by the Schläfli symbol (47·63)(47·68) as a novel 3D (5,6)-connected net. Furthermore, the IR, TGA, PXRD, and UV−vis spectral and luminescent properties of 1−4 were also studied." @default.
• W2317204037 created "2016-06-24" @default.
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• W2317204037 date "2007-11-09" @default.
• W2317204037 modified "2023-09-25" @default.
• W2317204037 title "{Ln^III[μ₅-κ²,κ¹,κ¹,κ¹,κ¹-1,2-(CO₂)₂C₆H₄][isonicotine][H₂O]}₂Cu^I·X (Ln = Eu, Sm, Nd; X = ClO₄^-, Cl^-): A New Pillared-Layer Approach to Heterobimetallic 3d−4f 3D-Network Solids" @default.
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• W2317204037 doi "https://doi.org/10.1021/ic700893w" @default.
• W2317204037 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17990870" @default.
• W2317204037 hasPublicationYear "2007" @default.
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