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- W2317247265 abstract "We report colloidal synthesis of antimony (Sb) nanocrystals with mean size tunable in the 10-20 nm range and with narrow size distributions of 7-11%. In comparison to microcrystalline Sb, 10 and 20 nm Sb nanocrystals exhibit enhanced rate-capability and higher cycling stability as anode materials in rechargeable Li-ion and Na-ion batteries. All three particle sizes of Sb possess high and similar Li-ion and Na-ion charge storage capacities of 580-640 mAh g(-1) at moderate charging/discharging current densities of 0.5-1C (1C-rate is 660 mA g(-1)). At all C-rates (0.5-20C, e.g. current densities of 0.33-13.2 Ag(1-)), capacities of 20 nm Sb particles are systematically better than for both 10 nm and bulk Sb. At 20C-rates, retention of charge storage capacities by 10 and 20 nm Sb nanocrystals can reach 78-85% of the low-rate value, indicating that rate capability of Sb nanostructures can be comparable to the best Li-ion intercalation anodes and is so far unprecedented for Na-ion storage." @default.
- W2317247265 created "2016-06-24" @default.
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- W2317247265 creator A5034871143 @default.
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- W2317247265 date "2014-02-04" @default.
- W2317247265 modified "2023-10-12" @default.
- W2317247265 title "Monodisperse Antimony Nanocrystals for High-Rate Li-ion and Na-ion Battery Anodes: Nano versus Bulk" @default.
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- W2317247265 doi "https://doi.org/10.1021/nl404165c" @default.
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