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• W2317249232 endingPage "545" @default.
• W2317249232 startingPage "534" @default.
• W2317249232 abstract "A series of cyclometalated PdII complexes that contain π-extended RC^N^NR′ (RC^N^NR′=3-(6′-aryl-2′-pyridinyl)isoquinoline) and chloride/pentafluorophenylacetylide ligands have been synthesized and their photophysical and photochemical properties examined. The complexes with the chloride ligand are emissive only in the solid state and in glassy solutions at 77 K, whereas the ones with the pentafluorophenylacetylide ligand show phosphorescence in the solid state (λmax=584–632 nm) and in solution (λmax=533–602 nm) at room temperature. Some of the complexes with the pentafluorophenylacetylide ligand show emission with λmax at 585–602 nm upon an increase in the complex concentration in solutions. These PdII complexes can act as photosensitizers for the light-induced aerobic oxidation of amines. In the presence of 0.1 mol % PdII complex, secondary amines can be oxidized to the corresponding imines with substrate conversions and product yields up to 100 and 99 %, respectively. In the presence of 0.15 mol % PdII complex, the oxidative cyanation of tertiary amines could be performed with product yields up to 91 %. The PdII complexes have also been used to sensitize photochemical hydrogen production with a three-component system that comprises the PdII complex, [Co(dmgH)2(py)Cl] (dmgH=dimethylglyoxime; py=pyridine), and triethanolamine, and a maximum turnover of hydrogen production of 175 in 4 h was achieved. The excited-state electron-transfer properties of the PdII complexes have been examined." @default.
• W2317249232 created "2016-06-24" @default.
• W2317249232 creator A5002062867 @default.
• W2317249232 creator A5014907489 @default.
• W2317249232 creator A5026763762 @default.
• W2317249232 creator A5071447194 @default.
• W2317249232 date "2013-11-07" @default.
• W2317249232 modified "2023-10-16" @default.
• W2317249232 title "Luminescent Palladium(II) Complexes with π-Extended Cyclometalated [RC^N^NR′] and Pentafluorophenylacetylide Ligands: Spectroscopic, Photophysical, and Photochemical Properties" @default.
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• W2317249232 doi "https://doi.org/10.1002/asia.201301059" @default.
• W2317249232 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24203620" @default.
• W2317249232 hasPublicationYear "2013" @default.
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