Matches in SemOpenAlex for { <https://semopenalex.org/work/W2317249797> ?p ?o ?g. }
- W2317249797 endingPage "993" @default.
- W2317249797 startingPage "983" @default.
- W2317249797 abstract "The air- and moisture-insensitive half-sandwich complexes [(η5-Cp*)Rh(L)Cl][PF6] (1–3) and [(η5-Cp*)Ir(L)Cl][PF6] (4–6) have been prepared by reacting L = L1–L3 (1,2-bis(phenylthio)ethane (L1), 1-(phenylseleno)-2-(phenylthio)ethane (L2) and 1,2-bis(phenylseleno)ethane (L3)) with [(η5-Cp*)RhCl(μ-Cl)]2 and [(η5-Cp*)IrCl(μ-Cl)]2, respectively, at room temperature followed by treatment with NH4PF6. Their HR-MS and 1H, 13C{1H}, and 77Se{1H} NMR spectra have authenticated them. The single-crystal structures of 1–6 have been established by X-ray crystallography. Complexes 1–6 have been explored for catalytic Oppenauer-type oxidation of alcohols and transfer hydrogenation of ketones with 2-propanol. 3 and 6 were the most efficient in the two catalytic reactions (TON values up to 9.9 × 102 and 9.8 × 103, respectively) and were therefore investigated in detail. 3 is the first example of a Rh(III) species explored for Oppenauer-type oxidation. The catalysis appears to be homogeneous. In transfer hydrogenation it app..." @default.
- W2317249797 created "2016-06-24" @default.
- W2317249797 creator A5016717376 @default.
- W2317249797 creator A5020145710 @default.
- W2317249797 creator A5079361519 @default.
- W2317249797 creator A5088636673 @default.
- W2317249797 creator A5089925942 @default.
- W2317249797 date "2014-02-11" @default.
- W2317249797 modified "2023-10-14" @default.
- W2317249797 title "(η<sup>5</sup>-Cp*)Rh(III)/Ir(III) Complexes with Bis(chalcogenoethers) (E, E′ Ligands: E = S/Se; E′ = S/Se): Synthesis, Structure, and Applications in Catalytic Oppenauer-Type Oxidation and Transfer Hydrogenation" @default.
- W2317249797 cites W1556644107 @default.
- W2317249797 cites W1964060855 @default.
- W2317249797 cites W1964919046 @default.
- W2317249797 cites W1965139687 @default.
- W2317249797 cites W1966182479 @default.
- W2317249797 cites W1966301144 @default.
- W2317249797 cites W1966726292 @default.
- W2317249797 cites W1970671842 @default.
- W2317249797 cites W1970800627 @default.
- W2317249797 cites W1970989368 @default.
- W2317249797 cites W1973089281 @default.
- W2317249797 cites W1977742205 @default.
- W2317249797 cites W1977829043 @default.
- W2317249797 cites W1980448786 @default.
- W2317249797 cites W1981158628 @default.
- W2317249797 cites W1981328271 @default.
- W2317249797 cites W1984237201 @default.
- W2317249797 cites W1985498430 @default.
- W2317249797 cites W1985842075 @default.
- W2317249797 cites W1986129072 @default.
- W2317249797 cites W1987060538 @default.
- W2317249797 cites W1988844076 @default.
- W2317249797 cites W1990916863 @default.
- W2317249797 cites W1994822130 @default.
- W2317249797 cites W1998022087 @default.
- W2317249797 cites W2002507671 @default.
- W2317249797 cites W2005257160 @default.
- W2317249797 cites W2007853088 @default.
- W2317249797 cites W2008708918 @default.
- W2317249797 cites W2009370325 @default.
- W2317249797 cites W2009761931 @default.
- W2317249797 cites W2011331598 @default.
- W2317249797 cites W2011485807 @default.
- W2317249797 cites W2012028316 @default.
- W2317249797 cites W2012341247 @default.
- W2317249797 cites W2013717176 @default.
- W2317249797 cites W2014378918 @default.
- W2317249797 cites W2016318768 @default.
- W2317249797 cites W2018006682 @default.
- W2317249797 cites W2018136594 @default.
- W2317249797 cites W2018537314 @default.
- W2317249797 cites W2019974637 @default.
- W2317249797 cites W2021357316 @default.
- W2317249797 cites W2026547785 @default.
- W2317249797 cites W2028257896 @default.
- W2317249797 cites W2029197481 @default.
- W2317249797 cites W2029609586 @default.
- W2317249797 cites W2033288172 @default.
- W2317249797 cites W2033482065 @default.
- W2317249797 cites W2036234553 @default.
- W2317249797 cites W2038882751 @default.
- W2317249797 cites W2040549881 @default.
- W2317249797 cites W2042271305 @default.
- W2317249797 cites W2042819548 @default.
- W2317249797 cites W2043532815 @default.
- W2317249797 cites W2043989603 @default.
- W2317249797 cites W2051377738 @default.
- W2317249797 cites W2052034062 @default.
- W2317249797 cites W2054974048 @default.
- W2317249797 cites W2058922650 @default.
- W2317249797 cites W2059556181 @default.
- W2317249797 cites W2061599957 @default.
- W2317249797 cites W2067249531 @default.
- W2317249797 cites W2068354019 @default.
- W2317249797 cites W2068470814 @default.
- W2317249797 cites W2068617439 @default.
- W2317249797 cites W2071605919 @default.
- W2317249797 cites W2072444901 @default.
- W2317249797 cites W2072469362 @default.
- W2317249797 cites W2072823260 @default.
- W2317249797 cites W2072854702 @default.
- W2317249797 cites W2073888473 @default.
- W2317249797 cites W2074962929 @default.
- W2317249797 cites W2075718665 @default.
- W2317249797 cites W2079282056 @default.
- W2317249797 cites W2080702699 @default.
- W2317249797 cites W2084335376 @default.
- W2317249797 cites W2085106254 @default.
- W2317249797 cites W2087550249 @default.
- W2317249797 cites W2089107890 @default.
- W2317249797 cites W2090690504 @default.
- W2317249797 cites W2091548448 @default.
- W2317249797 cites W2091548988 @default.
- W2317249797 cites W2092816490 @default.
- W2317249797 cites W2093025471 @default.
- W2317249797 cites W2096434365 @default.
- W2317249797 cites W2098951988 @default.
- W2317249797 cites W2102706205 @default.