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- W2317294582 abstract "Abstract Thermolyses and reactions with nucleophiles of S,S-diphenylsulfoximines (1) bearing the following N-sulfur-substituents, i.e., N-p-tolylthio-(b), N-p-tolylsulfinyl-(c), N-(N′-p-tolylsulfonyl-p-toluenesulfinimidoyl)-(d), N-(S′,S′-diphenylsulfonio)-(e), N-p-tolylsulfonyl-(f), and N-(N′-p-tolylsulfonyl-p-toluenesul-fonimidoyl)-(g), have been examined. The former three sulfoximines (1b-d) are thermally unstable and readily decompose to form diphenyl sulfoxide and diphenyl sulfide by the initial cleavage of the S[sbnd]N linkage in the original sulfoximines. The latter three sulfoximines (1e-g) fairly stable thermally. 1b-d were found to react with several nucleophiles to afford the corresponding sulfenylated, sulfinylated or sulfinimidoylated products together with N-unsubstituted sulfoximine (1a). 1e was found to react with potassium hydroxide/methanol or chloramine-T/N,N-dimethylformamide to afford diphenyl sulfoxide or S,S-diphenyl-(N-p-tolylsulfonyl)sulfilimine along with 1a in good yields. The la..." @default.
- W2317294582 created "2016-06-24" @default.
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- W2317294582 date "1985-10-29" @default.
- W2317294582 modified "2023-09-26" @default.
- W2317294582 title "ChemInform Abstract: THERMOLYSES AND REACTIONS WITH NUCLEOPHILES OF N-SULFUR-GROUP-SUBSTITUTED SULFOXIMINES" @default.
- W2317294582 cites W4254018341 @default.
- W2317294582 doi "https://doi.org/10.1002/chin.198543109" @default.
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