Matches in SemOpenAlex for { <https://semopenalex.org/work/W2317302445> ?p ?o ?g. }
- W2317302445 endingPage "1911" @default.
- W2317302445 startingPage "1903" @default.
- W2317302445 abstract "Room-temperature photolysis of the aminoboryl complex [(OC)(5)Cr═B═N(SiMe(3))(2)] in the presence of a series of mono- or bis(boryl) alkynes bis{bis(dimethylamino)boryl}ethyne, 1-phenyl-2-bis(dimethylamino)borylethyne, and 1-trimethylsilyl-2-bis(dimethylamino)borylethyne led to the isolation of hitherto unknown borylborirenes in resonable yields, that is, [(RC═CR')(μ-BN(SiMe(3))(2))] (7, R = B(NMe(2))(2), R' = Ph; 8, R = R' = B(NMe(2))(2); 9, R = B(NMe(2))(2), R' = SiMe(3)). The borirenes were isolated and spectroscopically characterized by multinuclear NMR, IR, and UV/vis spectroscopy, crystallography, and elemental analysis. Reactivity studies of the borirenes demonstrated their behavior toward different Lewis bases. The isolated adducts and the parent borirenes were compared to 1,3-mesityl-2-phenylborirene and its adducts. To gain insight into the electronic structure and to evaluate the influence of the exocyclic groups, Density Functional Theory (DFT) calculations were carried out." @default.
- W2317302445 created "2016-06-24" @default.
- W2317302445 creator A5011223450 @default.
- W2317302445 creator A5015756937 @default.
- W2317302445 creator A5025949281 @default.
- W2317302445 creator A5038029240 @default.
- W2317302445 creator A5048371616 @default.
- W2317302445 creator A5056569207 @default.
- W2317302445 creator A5075230954 @default.
- W2317302445 creator A5084536262 @default.
- W2317302445 date "2013-01-24" @default.
- W2317302445 modified "2023-10-18" @default.
- W2317302445 title "Electronic and Structural Effects of Stepwise Borylation and Quaternization on Borirene Aromaticity" @default.
- W2317302445 cites W116545228 @default.
- W2317302445 cites W142523527 @default.
- W2317302445 cites W1553557746 @default.
- W2317302445 cites W1963515259 @default.
- W2317302445 cites W1968962542 @default.
- W2317302445 cites W1971044271 @default.
- W2317302445 cites W1973400133 @default.
- W2317302445 cites W1982090940 @default.
- W2317302445 cites W1983794742 @default.
- W2317302445 cites W1985515646 @default.
- W2317302445 cites W1989540267 @default.
- W2317302445 cites W1995340271 @default.
- W2317302445 cites W1996919984 @default.
- W2317302445 cites W1997690495 @default.
- W2317302445 cites W2007986558 @default.
- W2317302445 cites W2008192551 @default.
- W2317302445 cites W2010735635 @default.
- W2317302445 cites W2011793611 @default.
- W2317302445 cites W2011822711 @default.
- W2317302445 cites W2013657098 @default.
- W2317302445 cites W2014705651 @default.
- W2317302445 cites W2015358601 @default.
- W2317302445 cites W2019490516 @default.
- W2317302445 cites W2019512570 @default.
- W2317302445 cites W2022395735 @default.
- W2317302445 cites W2030430725 @default.
- W2317302445 cites W2031589128 @default.
- W2317302445 cites W2041623685 @default.
- W2317302445 cites W2043872748 @default.
- W2317302445 cites W2046660858 @default.
- W2317302445 cites W2051411840 @default.
- W2317302445 cites W2052034295 @default.
- W2317302445 cites W2056111309 @default.
- W2317302445 cites W2056784313 @default.
- W2317302445 cites W2062348717 @default.
- W2317302445 cites W2063715453 @default.
- W2317302445 cites W2066433440 @default.
- W2317302445 cites W2066553969 @default.
- W2317302445 cites W2069618700 @default.
- W2317302445 cites W2070005238 @default.
- W2317302445 cites W2073424172 @default.
- W2317302445 cites W2075888866 @default.
- W2317302445 cites W2079071600 @default.
- W2317302445 cites W2091258582 @default.
- W2317302445 cites W2092451460 @default.
- W2317302445 cites W2092527930 @default.
- W2317302445 cites W2102890851 @default.
- W2317302445 cites W2121237359 @default.
- W2317302445 cites W2131144399 @default.
- W2317302445 cites W2133300466 @default.
- W2317302445 cites W2152420176 @default.
- W2317302445 cites W2154752845 @default.
- W2317302445 cites W2312313243 @default.
- W2317302445 cites W2949984959 @default.
- W2317302445 cites W2950394030 @default.
- W2317302445 cites W4248190645 @default.
- W2317302445 cites W4294236040 @default.
- W2317302445 doi "https://doi.org/10.1021/ja3110126" @default.
- W2317302445 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23305227" @default.
- W2317302445 hasPublicationYear "2013" @default.
- W2317302445 type Work @default.
- W2317302445 sameAs 2317302445 @default.
- W2317302445 citedByCount "39" @default.
- W2317302445 countsByYear W23173024452013 @default.
- W2317302445 countsByYear W23173024452014 @default.
- W2317302445 countsByYear W23173024452015 @default.
- W2317302445 countsByYear W23173024452016 @default.
- W2317302445 countsByYear W23173024452017 @default.
- W2317302445 countsByYear W23173024452018 @default.
- W2317302445 countsByYear W23173024452019 @default.
- W2317302445 countsByYear W23173024452020 @default.
- W2317302445 countsByYear W23173024452021 @default.
- W2317302445 countsByYear W23173024452022 @default.
- W2317302445 countsByYear W23173024452023 @default.
- W2317302445 crossrefType "journal-article" @default.
- W2317302445 hasAuthorship W2317302445A5011223450 @default.
- W2317302445 hasAuthorship W2317302445A5015756937 @default.
- W2317302445 hasAuthorship W2317302445A5025949281 @default.
- W2317302445 hasAuthorship W2317302445A5038029240 @default.
- W2317302445 hasAuthorship W2317302445A5048371616 @default.
- W2317302445 hasAuthorship W2317302445A5056569207 @default.
- W2317302445 hasAuthorship W2317302445A5075230954 @default.
- W2317302445 hasAuthorship W2317302445A5084536262 @default.
- W2317302445 hasConcept C108204754 @default.
- W2317302445 hasConcept C142724271 @default.