FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2317323977> ?p ?o ?g. }

• W2317323977 endingPage "939" @default.
• W2317323977 startingPage "931" @default.
• W2317323977 abstract "The crystal structure of a natural F-bearing chondrodite [Mg4.64Fe0.28Mn0.014Ti0.023(Si1.01O4)2F1.16OH0.84; a = 4.7328(1), b = 10.2749(2), c = 7.8756(1) Å, a = 109.065(1)∞; space group P21/b (a unique)] from the Tilly Foster mine (Brewster, New York) and the structure of a deuterated synthetic analogue [Mg5(SiO4)2F1.10OD0.90] were refined at high pressure using single-crystal X-ray and time-of-flight neutron powder diffraction data, respectively. The isothermal equation of state was determined from single-crystal high-precision X-ray diffraction measurements of unit-cell parameters as a function of pressure up to 9.63(1) GPa. A third-order Birch-Murnaghan equation-of-state fit to pressurevolume data results in V0 = 362.00(2) Å3, K0,T = 117.0(4) GPa and KT' = 5.6(1). The larger value of K0,T relative to that determined for the OH end-member confirms that F makes the chondrodite structure less compressible. The axial compressibilities behave anisotropically with fitted parameters a0 = 4.73282(9) Å, K(a)0 = 458(3) GPa, and K(a)' = 28.9(9); b0 = 10.2759(3) Å, K(b)0 = 298(1) GPa, and K(b)' = 13.4(4); c0 = 7.8759(2) Å, K(c)0 = 316(2) GPa, and K(c)' = 16.7(5). X-ray structural investigations at 0.0001, 4.952(7), and 9.550(7) GPa in a diamond-anvil cell reveal a complex compression mechanism. The greatest changes with pressure occur in the M2 octahedra, which are located at the flexion points of the octahedral chain. These octahedra have the longest bonds at ambient conditions due to cation-cation repulsion, which displaces the cation from the centroid of the octahedron. The application of pressure overcomes the effect of cation-cation repulsion inducing a strong bond-length compression. The neutron powder data were collected at 0.0001, 1.26(1), 2.89(2), 3.87(1), 5.27(2), and 7.04(2) GPa in the Paris-Edinburgh cell using a new gasket design and a fluid pressure medium. Changes in the O-D···O/F hydrogen bond geometry with pressure can be interpreted in terms of a rotation of the OD vector and a reduction in the degree of static disorder associated with the hydrogen bond acceptor/donor site. These new crystallographic data are discussed in terms of corresponding spectroscopic measurements reported recently in the literature" @default.
• W2317323977 created "2016-06-24" @default.
• W2317323977 creator A5038444727 @default.
• W2317323977 creator A5040819691 @default.
• W2317323977 creator A5043832475 @default.
• W2317323977 creator A5053738196 @default.
• W2317323977 creator A5089497883 @default.
• W2317323977 date "2002-07-01" @default.
• W2317323977 modified "2023-10-18" @default.
• W2317323977 title "High-pressure single-crystal X-ray and powder neutron study of F,OH/OD-chondrodite: Compressibility, structure, and hydrogen bonding" @default.
• W2317323977 cites W1633619118 @default.
• W2317323977 cites W1831710731 @default.
• W2317323977 cites W1977202349 @default.
• W2317323977 cites W1978890814 @default.
• W2317323977 cites W1980536281 @default.
• W2317323977 cites W1980939448 @default.
• W2317323977 cites W1993148996 @default.
• W2317323977 cites W1998326947 @default.
• W2317323977 cites W2005172827 @default.
• W2317323977 cites W2005481160 @default.
• W2317323977 cites W2006815166 @default.
• W2317323977 cites W2008018465 @default.
• W2317323977 cites W2014282312 @default.
• W2317323977 cites W2016260972 @default.
• W2317323977 cites W2023709137 @default.
• W2317323977 cites W2027581929 @default.
• W2317323977 cites W2030074823 @default.
• W2317323977 cites W2048666518 @default.
• W2317323977 cites W2048790604 @default.
• W2317323977 cites W2053767862 @default.
• W2317323977 cites W2060215309 @default.
• W2317323977 cites W2071941383 @default.
• W2317323977 cites W2074749273 @default.
• W2317323977 cites W2076849661 @default.
• W2317323977 cites W2080479191 @default.
• W2317323977 cites W2094315395 @default.
• W2317323977 cites W2110877783 @default.
• W2317323977 cites W2120518470 @default.
• W2317323977 cites W2126588056 @default.
• W2317323977 cites W2185756156 @default.
• W2317323977 cites W2188729233 @default.
• W2317323977 cites W2303064450 @default.
• W2317323977 cites W2303227244 @default.
• W2317323977 cites W2330046102 @default.
• W2317323977 cites W2338896234 @default.
• W2317323977 cites W2368318952 @default.
• W2317323977 cites W2408274829 @default.
• W2317323977 cites W2506232167 @default.
• W2317323977 cites W2568627164 @default.
• W2317323977 cites W2789563885 @default.
• W2317323977 cites W2908467104 @default.
• W2317323977 cites W3000682903 @default.
• W2317323977 doi "https://doi.org/10.2138/am-2002-0716" @default.
• W2317323977 hasPublicationYear "2002" @default.
• W2317323977 type Work @default.
• W2317323977 sameAs 2317323977 @default.
• W2317323977 citedByCount "38" @default.
• W2317323977 countsByYear W23173239772013 @default.
• W2317323977 countsByYear W23173239772015 @default.
• W2317323977 countsByYear W23173239772016 @default.
• W2317323977 countsByYear W23173239772017 @default.
• W2317323977 countsByYear W23173239772019 @default.
• W2317323977 countsByYear W23173239772020 @default.
• W2317323977 countsByYear W23173239772021 @default.
• W2317323977 countsByYear W23173239772022 @default.
• W2317323977 countsByYear W23173239772023 @default.
• W2317323977 crossrefType "journal-article" @default.
• W2317323977 hasAuthorship W2317323977A5038444727 @default.
• W2317323977 hasAuthorship W2317323977A5040819691 @default.
• W2317323977 hasAuthorship W2317323977A5043832475 @default.
• W2317323977 hasAuthorship W2317323977A5053738196 @default.
• W2317323977 hasAuthorship W2317323977A5089497883 @default.
• W2317323977 hasConcept C115624301 @default.
• W2317323977 hasConcept C120665830 @default.
• W2317323977 hasConcept C121332964 @default.
• W2317323977 hasConcept C133347239 @default.
• W2317323977 hasConcept C184779094 @default.
• W2317323977 hasConcept C185039092 @default.
• W2317323977 hasConcept C185592680 @default.
• W2317323977 hasConcept C207114421 @default.
• W2317323977 hasConcept C23455440 @default.
• W2317323977 hasConcept C2984729377 @default.
• W2317323977 hasConcept C50515024 @default.
• W2317323977 hasConcept C53810900 @default.
• W2317323977 hasConcept C58364064 @default.
• W2317323977 hasConcept C73585123 @default.
• W2317323977 hasConcept C73922627 @default.
• W2317323977 hasConcept C8010536 @default.
• W2317323977 hasConcept C84655787 @default.
• W2317323977 hasConcept C97355855 @default.
• W2317323977 hasConceptScore W2317323977C115624301 @default.
• W2317323977 hasConceptScore W2317323977C120665830 @default.
• W2317323977 hasConceptScore W2317323977C121332964 @default.
• W2317323977 hasConceptScore W2317323977C133347239 @default.
• W2317323977 hasConceptScore W2317323977C184779094 @default.
• W2317323977 hasConceptScore W2317323977C185039092 @default.
• W2317323977 hasConceptScore W2317323977C185592680 @default.
• W2317323977 hasConceptScore W2317323977C207114421 @default.

• next