Matches in SemOpenAlex for { <https://semopenalex.org/work/W2317365867> ?p ?o ?g. }
Showing items 1 to 89 of
89
with 100 items per page.
- W2317365867 endingPage "486" @default.
- W2317365867 startingPage "483" @default.
- W2317365867 abstract "The specific rates of solvolysis of α, p-dichloroanisole (chloromethyl p-chlorophenyl ether, 1) have been measured conductimetrically in a variety of hydroxylic solvents. In three typical solvents, at 25.0 °C, the rate is 20–45 times greater than for the corresponding sulfide. In a comparison with the solvolysis of a substrate with an alkyl group replacing the aryl group, chloromethyl ethyl ether (2), at −10.0 °C in four typical solvents, 1 reacted considerably more slowly than 2, by a little over four orders of magnitude. An extended Grunwald–Winstein equation treatment of the specific rates of solvolyses in 24 solvents at 25.0 °C leads to an l value of 0.68 ± 0.04 and an m value of 0.59 ± 0.03 ( l/ m = 1.15). Appreciable nucleophilic assistance in the progress to the transition state is indicated and either nucleophilic solvation to an ionisation process or a loose S N 2 transition state with extensive bond-breaking accompanied by a smaller degree of bond-making lead to an appropriate transition state." @default.
- W2317365867 created "2016-06-24" @default.
- W2317365867 creator A5014902913 @default.
- W2317365867 creator A5058956045 @default.
- W2317365867 date "2013-08-01" @default.
- W2317365867 modified "2023-09-27" @default.
- W2317365867 title "Extent of Nucleophilic Participation in the Solvolyses of an Aryl Chloromethyl Ether, α, p-Dichloroanisole" @default.
- W2317365867 cites W1964435894 @default.
- W2317365867 cites W1978720780 @default.
- W2317365867 cites W1989185986 @default.
- W2317365867 cites W1995449282 @default.
- W2317365867 cites W2004769764 @default.
- W2317365867 cites W2013357093 @default.
- W2317365867 cites W2014193593 @default.
- W2317365867 cites W2021468143 @default.
- W2317365867 cites W2033425159 @default.
- W2317365867 cites W2040383509 @default.
- W2317365867 cites W2056559909 @default.
- W2317365867 cites W2074540587 @default.
- W2317365867 cites W2082906901 @default.
- W2317365867 cites W2089177356 @default.
- W2317365867 cites W2094720373 @default.
- W2317365867 cites W2313098018 @default.
- W2317365867 cites W2323189773 @default.
- W2317365867 cites W2949295849 @default.
- W2317365867 cites W2951864437 @default.
- W2317365867 cites W4211081305 @default.
- W2317365867 cites W4233048363 @default.
- W2317365867 cites W84151782 @default.
- W2317365867 doi "https://doi.org/10.3184/174751913x13734534378121" @default.
- W2317365867 hasPublicationYear "2013" @default.
- W2317365867 type Work @default.
- W2317365867 sameAs 2317365867 @default.
- W2317365867 citedByCount "1" @default.
- W2317365867 countsByYear W23173658672016 @default.
- W2317365867 crossrefType "journal-article" @default.
- W2317365867 hasAuthorship W2317365867A5014902913 @default.
- W2317365867 hasAuthorship W2317365867A5058956045 @default.
- W2317365867 hasConcept C135731615 @default.
- W2317365867 hasConcept C148093993 @default.
- W2317365867 hasConcept C155647269 @default.
- W2317365867 hasConcept C160964918 @default.
- W2317365867 hasConcept C161790260 @default.
- W2317365867 hasConcept C178790620 @default.
- W2317365867 hasConcept C178907741 @default.
- W2317365867 hasConcept C185592680 @default.
- W2317365867 hasConcept C2779293432 @default.
- W2317365867 hasConcept C2780263894 @default.
- W2317365867 hasConcept C2780407432 @default.
- W2317365867 hasConcept C2780471494 @default.
- W2317365867 hasConcept C2781076698 @default.
- W2317365867 hasConcept C89031862 @default.
- W2317365867 hasConcept C94412978 @default.
- W2317365867 hasConceptScore W2317365867C135731615 @default.
- W2317365867 hasConceptScore W2317365867C148093993 @default.
- W2317365867 hasConceptScore W2317365867C155647269 @default.
- W2317365867 hasConceptScore W2317365867C160964918 @default.
- W2317365867 hasConceptScore W2317365867C161790260 @default.
- W2317365867 hasConceptScore W2317365867C178790620 @default.
- W2317365867 hasConceptScore W2317365867C178907741 @default.
- W2317365867 hasConceptScore W2317365867C185592680 @default.
- W2317365867 hasConceptScore W2317365867C2779293432 @default.
- W2317365867 hasConceptScore W2317365867C2780263894 @default.
- W2317365867 hasConceptScore W2317365867C2780407432 @default.
- W2317365867 hasConceptScore W2317365867C2780471494 @default.
- W2317365867 hasConceptScore W2317365867C2781076698 @default.
- W2317365867 hasConceptScore W2317365867C89031862 @default.
- W2317365867 hasConceptScore W2317365867C94412978 @default.
- W2317365867 hasIssue "8" @default.
- W2317365867 hasLocation W23173658671 @default.
- W2317365867 hasOpenAccess W2317365867 @default.
- W2317365867 hasPrimaryLocation W23173658671 @default.
- W2317365867 hasRelatedWork W1564923129 @default.
- W2317365867 hasRelatedWork W1989604363 @default.
- W2317365867 hasRelatedWork W1993233603 @default.
- W2317365867 hasRelatedWork W2067615050 @default.
- W2317365867 hasRelatedWork W2122187582 @default.
- W2317365867 hasRelatedWork W2317365867 @default.
- W2317365867 hasRelatedWork W2324898221 @default.
- W2317365867 hasRelatedWork W2967800957 @default.
- W2317365867 hasRelatedWork W3004417546 @default.
- W2317365867 hasRelatedWork W4206475757 @default.
- W2317365867 hasVolume "37" @default.
- W2317365867 isParatext "false" @default.
- W2317365867 isRetracted "false" @default.
- W2317365867 magId "2317365867" @default.
- W2317365867 workType "article" @default.