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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2317372284> ?p ?o ?g. }

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• W2317372284 startingPage "3750" @default.
• W2317372284 abstract "α-Alkylated (dimethylsilyl)acetonitriles (Me2HSiCR3R4CN) react spontaneously with aldehydes in DMSO to give β-hydroxynitriles in good to high yields. The addition to ketones is effectively promoted by using MgCl2 or CaCl2. (Dimethylsilyl)acetonitrile (Me2HSiCH2CN) shows lower reactivity than the α-alkylated analogues. However, the parent reagent adds efficiently to aldehydes and ketones under catalysis by AcOLi or MgCl2." @default.
• W2317372284 created "2016-06-24" @default.
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• W2317372284 date "2013-07-09" @default.
• W2317372284 modified "2023-10-01" @default.
• W2317372284 title "Nucleophilic Addition of α-(Dimethylsilyl)nitriles to Aldehydes and Ketones" @default.
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• W2317372284 doi "https://doi.org/10.1021/ol401663u" @default.
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