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- W2317376478 endingPage "3242" @default.
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- W2317376478 abstract "Complexation between a triptycene-derived macrotricyclic polyether containing two dibenzo-[30]-crown-10 cavities and different functionalized paraquat derivatives, diquat, and a 2,7-diazapyrenium salt in both solution and solid state was investigated in detail. It was found that depending on the guests with different terminal functional groups and structures, the macrotricyclic polyether could form 1:1 or 1:2 complexes with the guests in different complexation modes in solution and also in the solid state. Especially, the conformation of the macrotricyclic polyether was efficiently adjusted by the encapsulated guests, which was to some extent similar to substrate-induced fit of enzymes. Moreover, the binding and releasing of the guests in the complexes could be controlled by potassium ions." @default.
- W2317376478 created "2016-06-24" @default.
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- W2317376478 date "2013-03-06" @default.
- W2317376478 modified "2023-10-10" @default.
- W2317376478 title "Complexation of Triptycene-Derived Macrotricyclic Polyether with Paraquat Derivatives, Diquat, and a 2,7-Diazapyrenium Salt: Guest-Induced Conformational Changes of the Host" @default.
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- W2317376478 doi "https://doi.org/10.1021/jo400148b" @default.
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