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- W2317382887 abstract "Heat capacities, thermal conductivities and melting points of several condensed phosphates, both in crystalline and vitreous states, were measured. The effects of cations on the thermal properties were discussed in connection with structural characteristics of the phosphates.The heat capacity C50 per gram formula weight at 50°C of vitreous phosphate with the chemical formula xMmOn⋅(1-x) P2O5 could be expressed by an empirical equation C50=Ax+B(1-x). Coefficients A and B in the equation were between 7 and 16 and between 28 and 38, respectively, depending on the systems investigated.The gram-atomic heat capacity was lower for vitreous metaphosphate containing cation with high ionic potential than for that containing cation with low ionic potential. The heat capacity of metaphosphate seemed to be determined by a function of two characteristic temperatures which were related to the vibrations of cations and macroanions, respectively. A reasonable assumption is as follows:The characteristic temperature related to the macroanions does not change significantly with the change of cation in the metaphosphates. The macroanion skeletons are bound together more tightly by cations with higher ionic potential than by the cations with lower ionic potential. Therefore the characteristic temperature related to a cation with higher ionic potential is higher. The dependence of the gram-atomic heat capacity on the ionic potential of cation can be explained by the difference in cation-skeleton interaction, or, in other words, by the difference in the characteristic temperature related to cation.Both thermal conductivity of the vitreous metaphosphate and melting point of the crystalline metaphosphate increased with an increase of ionic potential of cation in the phosphates. This also can be explained in terms of the change of interaction between macroanions through cations." @default.
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- W2317382887 date "1971-01-01" @default.
- W2317382887 modified "2023-09-26" @default.
- W2317382887 title "Effects of Different Kinds of Cations on Thermal Properties of Condensed Phosphates" @default.
- W2317382887 doi "https://doi.org/10.2109/jcersj1950.79.906_49" @default.
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