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- W2317403192 abstract "Coordination-driven self-assembly utilizing labile capping ligands has been exploited as a novel strategy for metallo-cage containers. Herein, we report a tetrameric porphyrin barrel complex [C60⊂Zn814(H2O)4(OTs)12](OTs)4 (2) (OTs = p-CH3C6H4SO3) formed from a tetrakis(bipyridyl)porphyrin ligand 1, Zn(OTs)2, and a template guest, C60 fullerene. The tetrameric-barrel 2 contains two kinds of bis(bpy) ZnII centers coordinated by TsO– anions which serve as labile capping ligands in the formation of the finite structure of 2." @default.
- W2317403192 created "2016-06-24" @default.
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- W2317403192 date "2013-12-09" @default.
- W2317403192 modified "2023-10-18" @default.
- W2317403192 title "A C<sub>60</sub>-Templated Tetrameric Porphyrin Barrel Complex via Zinc-Mediated Self-Assembly Utilizing Labile Capping Ligands" @default.
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- W2317403192 doi "https://doi.org/10.1021/ja4110446" @default.
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