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• W2317484800 abstract "In this work, newly-developed MD-QCT databases for nitrogen dissociation cross sections and interal energy relaxation are implemented in DSMC simulations of heat bath cases and normal shocks in nitrogen and the results are compared with those obtained using the traditional TCE and LB models. In the heat bath cases the MD-QCT chemical reaction model predicts more dissociation and less nonequilibrium in the steady state and faster relaxation of the vibrational temperature compared with using the TCE-LB models. In the relatively low speed hypersonic one-dimensional unsteady shocks cases with conditions similar to those in the heat bath case, the flow field results exhibit similar behavior as those seen in the heat bath case when the MD-QCT cross sections are progressively added. Finally, for the higher speed shock conditions such as those in the experiments by Fujita et al., the use of MD-QCT cross sections for both chemical reaction and interal energy relaxation processes predicts more dissociation in the downstream region of the shock but slower relaxation of the rotational temperature than the baseline TCE and LB models. Furthermore, the rotational temperature in the shock region is in better agreement with experiments and confirms that large rotational nonequilibrium is present in very strong nitrogen shocks." @default.
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• W2317484800 date "2014-06-13" @default.
• W2317484800 modified "2023-10-03" @default.
• W2317484800 title "High Fidelity Modeling of Energy Transfer and Chemical Reactions in Shock Waves" @default.
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• W2317484800 doi "https://doi.org/10.2514/6.2014-3207" @default.
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