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• W2317502703 abstract "We have investigated p-terphenylthiol (TPT) adsorption on the Au(111) surfaces from dimethylformamide solution at 373 K. Scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy, and spectroscopic ellipsometry were used to follow the dynamics and explore the structure of the self-assembled monolayer on Au(111). This combined approach revealed that TPT molecules form self-assembled domains within the first seconds of Au surface exposure to thiol solution. The complete monolayer structure forms within ∼1 min. It presents itself as a well-ordered defect-free self-assembled monolayer. Further exposure does not introduce observable changes to the monolayer structure. Two competing phases (α and β) of differently packed molecules were observed within the first seconds of adsorption, with the β-phases dominating from 1 min. Close inspection of adsorbed TPT molecules with STM demonstrated their almost upright conformation on the surface with a tilt angle of 0 ± 5° in the β-phase and tilted (10–20°) conformation in the α-phase." @default.
• W2317502703 created "2016-06-24" @default.
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• W2317502703 date "2011-07-13" @default.
• W2317502703 modified "2023-09-27" @default.
• W2317502703 title "High-Temperature Adsorption of <i>p</i>-Terphenylthiol on Au(111) Surfaces" @default.
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• W2317502703 doi "https://doi.org/10.1021/jp203538g" @default.
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