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- W2317502714 abstract "The microstructure of C16TABr micelles with solubilized benzene was investigated by field-dependent 2H NMR spin relaxation of C16TABr-α-d2. The relaxation data, supported by cryogenic transmission electron microscopy that excludes oblate micelle shapes, suggest that the C16TABr micelles, slightly elongated even without benzene, become longer and more polydisperse on benzene addition. Field-dependent 2H spin relaxation measurements on the benzene (C6D6) indicate that at low solubilizate content the benzene is predominantly located at the micellar interface, reorients more slowly than in bulk, and has a high lateral diffusion coefficient. Above a particular benzene concentration, the surfactant relaxation data suggest no further elongation but a radial growth, while the benzene relaxation shows that a large part of the benzene is residing in an interior region with near-bulk characteristics; the micelles become slightly elongated microemulsion droplets." @default.
- W2317502714 created "2016-06-24" @default.
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- W2317502714 date "1999-10-16" @default.
- W2317502714 modified "2023-10-16" @default.
- W2317502714 title "Shape Changes of C<sub>16</sub>TABr Micelles on Benzene Solubilization" @default.
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- W2317502714 doi "https://doi.org/10.1021/jp991686o" @default.
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