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- W2317504744 abstract "A Pd/Ag bimetallic system has been developed for the decarboxylative allylation of ortho-nitrobenzoic esters in an intramolecular fashion. In contrast to the typical sp2–sp3 cross-coupling approach which requires air and moisture sensitive preformed organometallic reagents, we provide an alternative route to the synthesis of ortho-allyl nitroarenes from the corresponding ortho-nitrobenzoic acid derivatives. The reaction proceeds through a mechanistically distinct decarboxylative metalation pathway. A cooperative reactivity of palladium and silver is crucial for the reaction outcome." @default.
- W2317504744 created "2016-06-24" @default.
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- W2317504744 date "2014-07-23" @default.
- W2317504744 modified "2023-10-01" @default.
- W2317504744 title "Palladium(0)-Catalyzed Intramolecular Decarboxylative Allylation of Ortho Nitrobenzoic Esters" @default.
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- W2317504744 doi "https://doi.org/10.1021/ol5017349" @default.
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