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- W2317504920 abstract "Abstract Considerable experimental work on the crystallization of unstrained natural rubber, both vulcanized and unvulcanized, has been described previously. The rate of crystallization of raw rubber increases as the temperature at which the crystallization occurs is reduced, until a maximum value is attained at about −26° C. On lowering the temperature further, the rate decreases continuously. A similar temperature dependence is found for vulcanized rubber, although the rate at any given temperature is lower. Small quantities of certain impurities, for example, stearic acid, greatly increase the rate of crystallization of raw rubber. Such impurities are normally present in plantation smoked-sheet rubber, on which many of the reported measurements of rates of crystallization have been made. The measurements now reported have, therefore, been made with a purified rubber (deproteinized pale crepe) containing negligible quantities of the relevant impurities. Peroxide vulcanizates prepared from such a rubber have also been examined. The crystallization process was followed dilatometrically." @default.
- W2317504920 created "2016-06-24" @default.
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- W2317504920 date "1956-09-01" @default.
- W2317504920 modified "2023-09-26" @default.
- W2317504920 title "Crystallization in Natural Rubber. IV. Temperature Dependence" @default.
- W2317504920 doi "https://doi.org/10.5254/1.3542594" @default.
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