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• W2317532046 endingPage "8469" @default.
• W2317532046 startingPage "8463" @default.
• W2317532046 abstract "We investigated viscoelastic and photoresponsive properties of the microparticle/liquid-crystal (LC) composite gels. The mechanical strength of the colloidal gels can be widely tuned by varying particle concentrations. With increasing particle concentration, a storage modulus of the particle/LC composite gels increased and reached over 104 Pa, showing good self-supporting ability. We demonstrated for the first time that the particle/LC composite gels exhibited rapid and repetitive recovery of the mechanical strength after large-amplitude oscillatory breakdown. In addition, photoresponsive properties of the composite gels were investigated by the cis–trans photoisomerization of the azobenzene compound doped into the host LCs. The photochemical gel–sol transition could be repeatedly induced by changing the phase structure of the host LCs between nematic and isotropic, using the photoisomerization. The particle/LC composite gels can be applied to optically healable materials by the site-selective gel–sol transition based on the photochemical modulation of the phase structures of the host LCs." @default.
• W2317532046 created "2016-06-24" @default.
• W2317532046 creator A5039494641 @default.
• W2317532046 creator A5079582623 @default.
• W2317532046 date "2012-05-23" @default.
• W2317532046 modified "2023-10-18" @default.
• W2317532046 title "Viscoelastic and Photoresponsive Properties of Microparticle/Liquid-Crystal Composite Gels: Tunable Mechanical Strength along with Rapid-Recovery Nature and Photochemical Surface Healing using an Azobenzene Dopant" @default.
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• W2317532046 doi "https://doi.org/10.1021/la3001784" @default.
• W2317532046 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22616972" @default.
• W2317532046 hasPublicationYear "2012" @default.
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