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• W2317609380 startingPage "8807" @default.
• W2317609380 abstract "New heterogeneous hydrogenation catalysts, based on Pd nanoparticles and polypropyleneimine (PPI) dendrimers of the third generation that have been covalently grafted to a silica surface modified with polyallylamine (PAA) have been synthesized. The final products were characterized by TEM, XPS, and solid-state NMR spectroscopy. The synthesized materials are effective catalysts for selective hydrogenation of dienes to monoenes and phenyl acetylene to styrene at very high substrate/Pd ratios with turnover rates higher than related Pd nanoparticle catalysts. The synthesized catalysts can be reused without any loss of activity in the case of styrene and isoprene." @default.
• W2317609380 created "2016-06-24" @default.
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• W2317609380 date "2014-05-02" @default.
• W2317609380 modified "2023-10-16" @default.
• W2317609380 title "Pd Nanoparticles in Dendrimers Immobilized on Silica–Polyamine Composites as Catalysts for Selective Hydrogenation" @default.
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• W2317609380 doi "https://doi.org/10.1021/am501528a" @default.
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