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- W2317621330 abstract "The bulk ring-opening polymerization of renewable δ-decalactone using 1,5,7-triazabicyclo[4.4.0]dec-5-ene was carried out at temperatures between 7 and 110 °C. The equilibrium monomer concentration for reactions within this temperature range was used to determine the polymerization thermodynamic parameters (ΔHp = −17.1 ± 0.6 kJ mol–1, ΔSp = −54 ± 2 J mol–1 K–1) for δ-decalactone. The polymerization kinetics were established and high molar mass poly(δ-decalactone) was prepared with a glass transition temperature of −51 °C. Poly(δ-decalactone) samples with controlled molar mass and narrow molar mass distributions were realized by controlling the monomer conversion and initiator concentration. A high molar mass poly(lactide)-poly(δ-decalactone)-poly(lactide) triblock copolymer with a low polydispersity index was prepared by simple sequential addition of monomers. The product triblock exhibited two distinct glass transitions temperatures consistent with microphase segregation." @default.
- W2317621330 created "2016-06-24" @default.
- W2317621330 creator A5044358227 @default.
- W2317621330 creator A5061889011 @default.
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- W2317621330 date "2011-11-30" @default.
- W2317621330 modified "2023-09-25" @default.
- W2317621330 title "Bulk Ring-Opening Transesterification Polymerization of the Renewable δ-Decalactone Using an Organocatalyst" @default.
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- W2317621330 doi "https://doi.org/10.1021/mz200006s" @default.
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