FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2317669784> ?p ?o ?g. }

• W2317669784 endingPage "15165" @default.
• W2317669784 startingPage "15162" @default.
• W2317669784 abstract "Molecular mechanisms by which to increase the activity of a mechanophore might provide access to new chemical reactions and enhanced stress-responsive behavior in mechanochemically active polymeric materials. Here, single-molecule force spectroscopy reveals that the force-induced acceleration of the electrocyclic ring opening of gem-dichlorocyclopropanes (gDCC) is sensitive to the stereochemistry of an α-alkene substituent on the gDCC. On the ∼0.1 s time scale of the experiment, the force required to open the E-alkene-substituted gDCC was found to be 0.4 nN lower than that required in the corresponding Z-alkene isomer, despite the effectively identical force-free reactivities of the two isomers and the distance between the stereochemical permutation and the scissile bond of the mechanophore. Fitting the experimental data with a cusp model provides force-free activation lengths of 1.67 ± 0.05 and 1.20 ± 0.05 Å for the E and Z isomers, respectively, as compared to 1.65 and 1.24 Å derived from computational modeling." @default.
• W2317669784 created "2016-06-24" @default.
• W2317669784 creator A5001301299 @default.
• W2317669784 creator A5002963148 @default.
• W2317669784 creator A5025261772 @default.
• W2317669784 creator A5040462364 @default.
• W2317669784 creator A5050841727 @default.
• W2317669784 creator A5081394467 @default.
• W2317669784 creator A5082847059 @default.
• W2317669784 date "2014-10-21" @default.
• W2317669784 modified "2023-09-26" @default.
• W2317669784 title "A Remote Stereochemical Lever Arm Effect in Polymer Mechanochemistry" @default.
• W2317669784 cites W105014408 @default.
• W2317669784 cites W1669551441 @default.
• W2317669784 cites W1970446046 @default.
• W2317669784 cites W1970863842 @default.
• W2317669784 cites W1975507494 @default.
• W2317669784 cites W1980781458 @default.
• W2317669784 cites W1981950382 @default.
• W2317669784 cites W1982454916 @default.
• W2317669784 cites W1995647974 @default.
• W2317669784 cites W2002237790 @default.
• W2317669784 cites W2003466971 @default.
• W2317669784 cites W2010165618 @default.
• W2317669784 cites W2027435439 @default.
• W2317669784 cites W2031035786 @default.
• W2317669784 cites W2043412192 @default.
• W2317669784 cites W2046886357 @default.
• W2317669784 cites W2047060525 @default.
• W2317669784 cites W2047182279 @default.
• W2317669784 cites W2051769448 @default.
• W2317669784 cites W2058128681 @default.
• W2317669784 cites W2071609537 @default.
• W2317669784 cites W2095859689 @default.
• W2317669784 cites W2126501716 @default.
• W2317669784 cites W2129201801 @default.
• W2317669784 cites W2129671178 @default.
• W2317669784 cites W2165853772 @default.
• W2317669784 cites W2166884124 @default.
• W2317669784 cites W2317870047 @default.
• W2317669784 cites W2321513796 @default.
• W2317669784 cites W2327370759 @default.
• W2317669784 cites W2328878629 @default.
• W2317669784 doi "https://doi.org/10.1021/ja509585g" @default.
• W2317669784 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25322470" @default.
• W2317669784 hasPublicationYear "2014" @default.
• W2317669784 type Work @default.
• W2317669784 sameAs 2317669784 @default.
• W2317669784 citedByCount "81" @default.
• W2317669784 countsByYear W23176697842015 @default.
• W2317669784 countsByYear W23176697842016 @default.
• W2317669784 countsByYear W23176697842017 @default.
• W2317669784 countsByYear W23176697842018 @default.
• W2317669784 countsByYear W23176697842019 @default.
• W2317669784 countsByYear W23176697842020 @default.
• W2317669784 countsByYear W23176697842021 @default.
• W2317669784 countsByYear W23176697842022 @default.
• W2317669784 countsByYear W23176697842023 @default.
• W2317669784 crossrefType "journal-article" @default.
• W2317669784 hasAuthorship W2317669784A5001301299 @default.
• W2317669784 hasAuthorship W2317669784A5002963148 @default.
• W2317669784 hasAuthorship W2317669784A5025261772 @default.
• W2317669784 hasAuthorship W2317669784A5040462364 @default.
• W2317669784 hasAuthorship W2317669784A5050841727 @default.
• W2317669784 hasAuthorship W2317669784A5081394467 @default.
• W2317669784 hasAuthorship W2317669784A5082847059 @default.
• W2317669784 hasConcept C147597530 @default.
• W2317669784 hasConcept C161790260 @default.
• W2317669784 hasConcept C178790620 @default.
• W2317669784 hasConcept C185592680 @default.
• W2317669784 hasConcept C2776254738 @default.
• W2317669784 hasConcept C2778689049 @default.
• W2317669784 hasConcept C32909587 @default.
• W2317669784 hasConcept C508816927 @default.
• W2317669784 hasConcept C71240020 @default.
• W2317669784 hasConceptScore W2317669784C147597530 @default.
• W2317669784 hasConceptScore W2317669784C161790260 @default.
• W2317669784 hasConceptScore W2317669784C178790620 @default.
• W2317669784 hasConceptScore W2317669784C185592680 @default.
• W2317669784 hasConceptScore W2317669784C2776254738 @default.
• W2317669784 hasConceptScore W2317669784C2778689049 @default.
• W2317669784 hasConceptScore W2317669784C32909587 @default.
• W2317669784 hasConceptScore W2317669784C508816927 @default.
• W2317669784 hasConceptScore W2317669784C71240020 @default.
• W2317669784 hasFunder F4320337367 @default.
• W2317669784 hasFunder F4320338281 @default.
• W2317669784 hasFunder F4320338295 @default.
• W2317669784 hasIssue "43" @default.
• W2317669784 hasLocation W23176697841 @default.
• W2317669784 hasLocation W23176697842 @default.
• W2317669784 hasOpenAccess W2317669784 @default.
• W2317669784 hasPrimaryLocation W23176697841 @default.
• W2317669784 hasRelatedWork W1989692008 @default.
• W2317669784 hasRelatedWork W2076364111 @default.
• W2317669784 hasRelatedWork W2949568156 @default.
• W2317669784 hasRelatedWork W2950083444 @default.
• W2317669784 hasRelatedWork W2951305430 @default.
• W2317669784 hasRelatedWork W2952995821 @default.

• next