FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2317697987> ?p ?o ?g. }

• W2317697987 endingPage "3144" @default.
• W2317697987 startingPage "3139" @default.
• W2317697987 abstract "The reaction of C60 with Re3(μ-H)3(CO)11(NCMe) in refluxing chlorobenzene produces Re3(μ-H)3(CO)9(μ3-η2,η2,η2-C60) (1) in 50% yield. Initial decarbonylation of 1 with Me3NO/MeCN followed by reaction with PPh3 in boiling chlorobenzene affords Re3(μ-H)3(CO)8(PPh3)(μ3-η2,η2,η2-C60) (2) in a low yield (26%). Treatment of 1 with PhCH2NPPh3 at room temperature gives a benzyl isocyanide substituted product Re3(μ-H)3(CO)8(CNCH2Ph)(μ3-η2,η2,η2-C60) (3) in 53% yield. Compounds 1, 2, and 3 have been isolated as crystalline solids and characterized by spectroscopic (infrared, mass, 1H, 31P, and 13C NMR) and analytical data. The structure of 3 has been determined by a single-crystal X-ray diffraction study. The C60 ligand is coordinated to the trirhenium triangle in a μ3-η2,η2,η2 bonding mode, and the benzyl isocyanide ligand occupies an axial position of a rhenium atom. Electrochemical properties of 1 and 2 have been studied by cyclic voltammetry (CV) in chlorobenzene (CB) solutions. The general features of CV curves have revealed four reversible redox couples for 1 and 2 in the CB potential window. The CV results suggest that a C60-mediated electron transfer to the trirhenium center takes place in 12- species for 1 and 23- for 2." @default.
• W2317697987 created "2016-06-24" @default.
• W2317697987 creator A5006012402 @default.
• W2317697987 creator A5009755251 @default.
• W2317697987 creator A5025415011 @default.
• W2317697987 creator A5026270791 @default.
• W2317697987 creator A5047172089 @default.
• W2317697987 creator A5080555312 @default.
• W2317697987 creator A5084528068 @default.
• W2317697987 date "2001-06-07" @default.
• W2317697987 modified "2023-09-26" @default.
• W2317697987 title "Synthesis and Characterization of μ₃-η²,η²,η²-C₆₀ Trirhenium Hydrido Cluster Complexes" @default.
• W2317697987 cites W179642519 @default.
• W2317697987 cites W1975466962 @default.
• W2317697987 cites W1978265071 @default.
• W2317697987 cites W1983340497 @default.
• W2317697987 cites W1999189061 @default.
• W2317697987 cites W2000320923 @default.
• W2317697987 cites W2023151126 @default.
• W2317697987 cites W2030638563 @default.
• W2317697987 cites W2033201712 @default.
• W2317697987 cites W2033532285 @default.
• W2317697987 cites W2038715990 @default.
• W2317697987 cites W2048040403 @default.
• W2317697987 cites W2049263755 @default.
• W2317697987 cites W2053837005 @default.
• W2317697987 cites W2058904498 @default.
• W2317697987 cites W2061259546 @default.
• W2317697987 cites W2086840416 @default.
• W2317697987 cites W2127790710 @default.
• W2317697987 cites W2284047584 @default.
• W2317697987 cites W2321679911 @default.
• W2317697987 cites W2949844222 @default.
• W2317697987 cites W2952677416 @default.
• W2317697987 doi "https://doi.org/10.1021/om0101341" @default.
• W2317697987 hasPublicationYear "2001" @default.
• W2317697987 type Work @default.
• W2317697987 sameAs 2317697987 @default.
• W2317697987 citedByCount "30" @default.
• W2317697987 countsByYear W23176979872012 @default.
• W2317697987 countsByYear W23176979872013 @default.
• W2317697987 countsByYear W23176979872014 @default.
• W2317697987 countsByYear W23176979872018 @default.
• W2317697987 countsByYear W23176979872019 @default.
• W2317697987 countsByYear W23176979872021 @default.
• W2317697987 countsByYear W23176979872022 @default.
• W2317697987 crossrefType "journal-article" @default.
• W2317697987 hasAuthorship W2317697987A5006012402 @default.
• W2317697987 hasAuthorship W2317697987A5009755251 @default.
• W2317697987 hasAuthorship W2317697987A5025415011 @default.
• W2317697987 hasAuthorship W2317697987A5026270791 @default.
• W2317697987 hasAuthorship W2317697987A5047172089 @default.
• W2317697987 hasAuthorship W2317697987A5080555312 @default.
• W2317697987 hasAuthorship W2317697987A5084528068 @default.
• W2317697987 hasConcept C115624301 @default.
• W2317697987 hasConcept C116569031 @default.
• W2317697987 hasConcept C132190689 @default.
• W2317697987 hasConcept C134121241 @default.
• W2317697987 hasConcept C155647269 @default.
• W2317697987 hasConcept C161790260 @default.
• W2317697987 hasConcept C170493617 @default.
• W2317697987 hasConcept C178790620 @default.
• W2317697987 hasConcept C179104552 @default.
• W2317697987 hasConcept C185592680 @default.
• W2317697987 hasConcept C191897082 @default.
• W2317697987 hasConcept C192562407 @default.
• W2317697987 hasConcept C2776041390 @default.
• W2317697987 hasConcept C2776701986 @default.
• W2317697987 hasConcept C2777010268 @default.
• W2317697987 hasConcept C2777463227 @default.
• W2317697987 hasConcept C2780471494 @default.
• W2317697987 hasConcept C2781083472 @default.
• W2317697987 hasConcept C505216180 @default.
• W2317697987 hasConcept C544153396 @default.
• W2317697987 hasConcept C55493867 @default.
• W2317697987 hasConcept C8010536 @default.
• W2317697987 hasConceptScore W2317697987C115624301 @default.
• W2317697987 hasConceptScore W2317697987C116569031 @default.
• W2317697987 hasConceptScore W2317697987C132190689 @default.
• W2317697987 hasConceptScore W2317697987C134121241 @default.
• W2317697987 hasConceptScore W2317697987C155647269 @default.
• W2317697987 hasConceptScore W2317697987C161790260 @default.
• W2317697987 hasConceptScore W2317697987C170493617 @default.
• W2317697987 hasConceptScore W2317697987C178790620 @default.
• W2317697987 hasConceptScore W2317697987C179104552 @default.
• W2317697987 hasConceptScore W2317697987C185592680 @default.
• W2317697987 hasConceptScore W2317697987C191897082 @default.
• W2317697987 hasConceptScore W2317697987C192562407 @default.
• W2317697987 hasConceptScore W2317697987C2776041390 @default.
• W2317697987 hasConceptScore W2317697987C2776701986 @default.
• W2317697987 hasConceptScore W2317697987C2777010268 @default.
• W2317697987 hasConceptScore W2317697987C2777463227 @default.
• W2317697987 hasConceptScore W2317697987C2780471494 @default.
• W2317697987 hasConceptScore W2317697987C2781083472 @default.
• W2317697987 hasConceptScore W2317697987C505216180 @default.
• W2317697987 hasConceptScore W2317697987C544153396 @default.
• W2317697987 hasConceptScore W2317697987C55493867 @default.
• W2317697987 hasConceptScore W2317697987C8010536 @default.

• next