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• W2317701436 abstract "The interface properties of organic–organic heterojunctions (OOHs) between diindenoperylene (DIP) and copper hexadecafluorophthalocyanine (F16CuPc), including interface morphology, molecular orientation, and energy level alignment, have been investigated systematically by atomic force microscopy, in situ ultraviolet photoelectron spectroscopy (UPS), X-ray photoelectron spectroscopy (XPS), and synchrotron-based near-edge X-ray adsorption fine structure (NEXAFS) measurements. As revealed by NEXAFS measurements, DIP molecules adopt the standing orientation on the standing F16CuPc on the SiO2 substrate, while they have the lying-down configuration on the flat-lying F16CuPc on the highly oriented pyrolytic graphite substrate. From the UPS and XPS studies, there is a large interfacial charge transfer and a band-bending-like behavior in the standing DIP/F16CuPc OOHs, while the vacuum level is almost aligned at the lying-down DIP/F16CuPc OOH interface. We propose that the defects-induced gap states have a crucial effect on the observed orientation-dependent energy level alignment and band-bending behaviors at these OOHs interfaces." @default.
• W2317701436 created "2016-06-24" @default.
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• W2317701436 date "2011-11-15" @default.
• W2317701436 modified "2023-09-27" @default.
• W2317701436 title "Effect of Gap States on the Orientation-Dependent Energy Level Alignment at the DIP/F₁₆CuPc Donor–Acceptor Heterojunction Interfaces" @default.
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• W2317701436 doi "https://doi.org/10.1021/jp208645f" @default.
• W2317701436 hasPublicationYear "2011" @default.
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