FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2317702911> ?p ?o ?g. }

• W2317702911 endingPage "1285" @default.
• W2317702911 startingPage "1280" @default.
• W2317702911 abstract "The unique behaviors of Nafion nanothin films with thicknesses of 10 nm (ultrathin) and 160 nm (thin) were evaluated using variable-temperature and variable-humidity solid-state 1H NMR spectroscopy. These unprecedented measurements of nanothin films stacked within an NMR rotor represent a remarkable experimental achievement and demonstrate that 1H NMR spectroscopy of such minute amounts of ionomer might be possible within active catalyst layers in polymer electrolyte fuel-cell electrodes. This study was motivated by the observation, in a separate work, of thickness-dependent and highly suppressed conductivity in nanothin films of Nafion (4–300 nm) compared to counterpart free-standing Nafion membranes. Trends in the line width and, more precisely, the T2 relaxation, as probed using a Hahn echo, showed that the local mobility within the hydrogen-bonded domain is equivalent for 10 and 160 nm films and is governed by the fast exchange limit in terms of NMR time scales. Subtle differences in the chemical shift trends provide insight into the domain structures, where the 10 nm films show no changes whereas the thicker 160 nm films exhibit chemical shift trends that indicate a rearranging hydrogen-bonded network. Thus, it is inferred that domain structure formation is influenced by film thickness and that the interaction with the substrate becomes limiting as the film becomes thinner." @default.
• W2317702911 created "2016-06-24" @default.
• W2317702911 creator A5018737861 @default.
• W2317702911 creator A5024448368 @default.
• W2317702911 creator A5063053435 @default.
• W2317702911 creator A5087098755 @default.
• W2317702911 date "2015-01-08" @default.
• W2317702911 modified "2023-09-24" @default.
• W2317702911 title "¹H Solid-State NMR Study of Nanothin Nafion Films" @default.
• W2317702911 cites W1600956050 @default.
• W2317702911 cites W1971695521 @default.
• W2317702911 cites W1972585338 @default.
• W2317702911 cites W1974795801 @default.
• W2317702911 cites W1976394244 @default.
• W2317702911 cites W1977970230 @default.
• W2317702911 cites W1984717573 @default.
• W2317702911 cites W2010937881 @default.
• W2317702911 cites W2013436076 @default.
• W2317702911 cites W2015624158 @default.
• W2317702911 cites W2018651936 @default.
• W2317702911 cites W2025160892 @default.
• W2317702911 cites W2026376369 @default.
• W2317702911 cites W2058549920 @default.
• W2317702911 cites W2067931677 @default.
• W2317702911 cites W2087232351 @default.
• W2317702911 cites W2094255943 @default.
• W2317702911 cites W2118468064 @default.
• W2317702911 cites W2119929243 @default.
• W2317702911 cites W2321678847 @default.
• W2317702911 cites W2323587919 @default.
• W2317702911 cites W2331246418 @default.
• W2317702911 cites W4254297188 @default.
• W2317702911 doi "https://doi.org/10.1021/jp5086747" @default.
• W2317702911 hasPublicationYear "2015" @default.
• W2317702911 type Work @default.
• W2317702911 sameAs 2317702911 @default.
• W2317702911 citedByCount "24" @default.
• W2317702911 countsByYear W23177029112015 @default.
• W2317702911 countsByYear W23177029112016 @default.
• W2317702911 countsByYear W23177029112017 @default.
• W2317702911 countsByYear W23177029112018 @default.
• W2317702911 countsByYear W23177029112019 @default.
• W2317702911 countsByYear W23177029112020 @default.
• W2317702911 countsByYear W23177029112021 @default.
• W2317702911 countsByYear W23177029112022 @default.
• W2317702911 countsByYear W23177029112023 @default.
• W2317702911 crossrefType "journal-article" @default.
• W2317702911 hasAuthorship W2317702911A5018737861 @default.
• W2317702911 hasAuthorship W2317702911A5024448368 @default.
• W2317702911 hasAuthorship W2317702911A5063053435 @default.
• W2317702911 hasAuthorship W2317702911A5087098755 @default.
• W2317702911 hasConcept C113196181 @default.
• W2317702911 hasConcept C121332964 @default.
• W2317702911 hasConcept C127413603 @default.
• W2317702911 hasConcept C147789679 @default.
• W2317702911 hasConcept C153202636 @default.
• W2317702911 hasConcept C15744967 @default.
• W2317702911 hasConcept C15920480 @default.
• W2317702911 hasConcept C159985019 @default.
• W2317702911 hasConcept C17525397 @default.
• W2317702911 hasConcept C178790620 @default.
• W2317702911 hasConcept C185592680 @default.
• W2317702911 hasConcept C192562407 @default.
• W2317702911 hasConcept C2776029896 @default.
• W2317702911 hasConcept C2776171763 @default.
• W2317702911 hasConcept C2778665636 @default.
• W2317702911 hasConcept C42360764 @default.
• W2317702911 hasConcept C46141821 @default.
• W2317702911 hasConcept C521977710 @default.
• W2317702911 hasConcept C52859227 @default.
• W2317702911 hasConcept C66974803 @default.
• W2317702911 hasConcept C77805123 @default.
• W2317702911 hasConceptScore W2317702911C113196181 @default.
• W2317702911 hasConceptScore W2317702911C121332964 @default.
• W2317702911 hasConceptScore W2317702911C127413603 @default.
• W2317702911 hasConceptScore W2317702911C147789679 @default.
• W2317702911 hasConceptScore W2317702911C153202636 @default.
• W2317702911 hasConceptScore W2317702911C15744967 @default.
• W2317702911 hasConceptScore W2317702911C15920480 @default.
• W2317702911 hasConceptScore W2317702911C159985019 @default.
• W2317702911 hasConceptScore W2317702911C17525397 @default.
• W2317702911 hasConceptScore W2317702911C178790620 @default.
• W2317702911 hasConceptScore W2317702911C185592680 @default.
• W2317702911 hasConceptScore W2317702911C192562407 @default.
• W2317702911 hasConceptScore W2317702911C2776029896 @default.
• W2317702911 hasConceptScore W2317702911C2776171763 @default.
• W2317702911 hasConceptScore W2317702911C2778665636 @default.
• W2317702911 hasConceptScore W2317702911C42360764 @default.
• W2317702911 hasConceptScore W2317702911C46141821 @default.
• W2317702911 hasConceptScore W2317702911C521977710 @default.
• W2317702911 hasConceptScore W2317702911C52859227 @default.
• W2317702911 hasConceptScore W2317702911C66974803 @default.
• W2317702911 hasConceptScore W2317702911C77805123 @default.
• W2317702911 hasFunder F4320334593 @default.
• W2317702911 hasIssue "3" @default.
• W2317702911 hasLocation W23177029111 @default.
• W2317702911 hasOpenAccess W2317702911 @default.
• W2317702911 hasPrimaryLocation W23177029111 @default.

• next