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• W2317732827 abstract "Nitroxides have antioxidative activities toward lipid peroxidation, but the influence of steric factors is not known. We synthesized alkyl-substituted nitroxides at the α-position of the N-O moiety to enhance lipophilicity and the bulk effect. There was good correlation between the IC(50) and lipophilicity (log P(o/w)) of nitroxides with use of the thiobarbituric acid-reactive substances (TBARS) assay. Furthermore, an inhibitory effect on the TBARS assay was dependent upon the number and length of alkyl groups, though nitroxides had almost identical lipophilicity." @default.
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• W2317732827 date "2011-04-18" @default.
• W2317732827 modified "2023-10-18" @default.
• W2317732827 title "Structural Concept of Nitroxide As a Lipid Peroxidation Inhibitor" @default.
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• W2317732827 doi "https://doi.org/10.1021/jo200361p" @default.
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