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• W2317776319 endingPage "2528" @default.
• W2317776319 startingPage "2523" @default.
• W2317776319 abstract "The phase-transfer behavior of poly(acrylic acid) (PAA) particles from the hydrophobic ionic liquid N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium bis(trifluoromethanesulfonyl)amide phase to the water phase in the particle state, which we reported previously, was examined in more detail. PAA particles were prepared in the ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide ([Bmim][TFSA]) and the organic solvent chloroform and were extracted. The transfer of PAA particles to water in the particle state was also observed in [Bmim][TFSA] systems. In contrast, the transfer phenomenon was not observed in the chloroform system. It was clarified that water/oil interfacial tension γwo is an important parameter in the extraction of PAA in the particle state from the viewpoint of free energy. When the cationic surfactant tetradecyltrimethylammonium bromide, aqueous solution was used as the extraction medium, the PAA particles were extracted in the particle state from chloroform to water, in which γwo became as low as that of the ionic liquid. This suggests that the phase-transfer phenomenon of PAA particles in the particle state was induced by the ionic liquid’s unique property of low interfacial tension with water despite its high hydrophobic character." @default.
• W2317776319 created "2016-06-24" @default.
• W2317776319 creator A5048930001 @default.
• W2317776319 creator A5060074122 @default.
• W2317776319 creator A5069942492 @default.
• W2317776319 date "2012-01-27" @default.
• W2317776319 modified "2023-09-27" @default.
• W2317776319 title "Phase-Transfer Behavior of Cross-Linked Poly(acrylic acid) Particles Prepared by Dispersion Polymerization from Ionic Liquid to Water" @default.
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• W2317776319 doi "https://doi.org/10.1021/la2047883" @default.
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• W2317776319 hasPublicationYear "2012" @default.
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