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• W2317777445 endingPage "7926" @default.
• W2317777445 startingPage "7916" @default.
• W2317777445 abstract "Vibrational circular dichroism (VCD) chirality transfer occurs when an achiral molecule interacts with a chiral one and becomes VCD-active. Unlike for H-bonds, for organic electron donor-acceptor (EDA) complexes this phenomenon remains almost unknown. Here, the VCD chirality transfer from chiral quinine to achiral BF3 is studied at the B3LYP/aug-cc-pVDZ level. Accessibility of four quinine electron donor sites changes with conformation. Therefore, the quinine conformational landscape was explored and a considerable agreement between X-ray and the most stable conformer geometries was achieved. The BF3 complex through the aliphatic quinuclidine N atom is definitely dominating and is predicted to be easily recognizable in the VCD spectrum. Out of several VCD chirality transfer modes, the ν(s)(BF3) mode, the most intense in the entire VCD spectrum, satisfies the VCD mode robustness criterion and can be used for monitoring the chirality transfer phenomenon in quinine···BF3 system." @default.
• W2317777445 created "2016-06-24" @default.
• W2317777445 creator A5045864347 @default.
• W2317777445 creator A5078009239 @default.
• W2317777445 creator A5078239137 @default.
• W2317777445 creator A5080226074 @default.
• W2317777445 date "2012-07-23" @default.
• W2317777445 modified "2023-09-24" @default.
• W2317777445 title "On Vibrational Circular Dichroism Chirality Transfer in Electron Donor–Acceptor Complexes: A Prediction for the Quinine···BF₃ System" @default.
• W2317777445 cites W1582849918 @default.
• W2317777445 cites W1964379406 @default.
• W2317777445 cites W1966162595 @default.
• W2317777445 cites W1967698682 @default.
• W2317777445 cites W1968121280 @default.
• W2317777445 cites W1968853883 @default.
• W2317777445 cites W1969144237 @default.
• W2317777445 cites W1970410936 @default.
• W2317777445 cites W1972639399 @default.
• W2317777445 cites W1972748216 @default.
• W2317777445 cites W1977986278 @default.
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• W2317777445 cites W1985358849 @default.
• W2317777445 cites W1986346915 @default.
• W2317777445 cites W1986701202 @default.
• W2317777445 cites W1988711378 @default.
• W2317777445 cites W1990378425 @default.
• W2317777445 cites W1990993700 @default.
• W2317777445 cites W1993077801 @default.
• W2317777445 cites W1993664210 @default.
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• W2317777445 cites W2015719761 @default.
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• W2317777445 cites W2042935274 @default.
• W2317777445 cites W2046833357 @default.
• W2317777445 cites W2048631643 @default.
• W2317777445 cites W2053485197 @default.
• W2317777445 cites W2061046283 @default.
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• W2317777445 cites W2069876255 @default.
• W2317777445 cites W2078920089 @default.
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• W2317777445 cites W2087570661 @default.
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• W2317777445 cites W2145163796 @default.
• W2317777445 cites W2148941593 @default.
• W2317777445 cites W2158302966 @default.
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• W2317777445 doi "https://doi.org/10.1021/jp304955v" @default.
• W2317777445 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22765267" @default.
• W2317777445 hasPublicationYear "2012" @default.
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