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- W2317814896 abstract "While intensively investigated as a solar light absorber in photovoltaic applications, the use of α-chalcocite (α-Cu2S) as such has been hindered by its conversion to a copper-deficient, nonstoichiometric phase, djurleite. Here we study this transformation in copper sulfide nanoparticles. We discuss the relative stabilities of α-chalcocite and djurleite as synthesized here, how this influences the conditions for obtaining these phases, and the affect of the reaction conditions on the phase transformation rate. Nanoparticle phases are characterized by powder X-ray diffraction (PXRD) and differential scanning calorimetry (DSC). Size and morphology was characterized by transmission electron microscopy (TEM). Additionally, the α-chalcocite particles were characterized by UV/visible/NIR absorption spectroscopy (UV/vis/NIR) and energy dispersive X-ray spectroscopy (EDS)." @default.
- W2317814896 created "2016-06-24" @default.
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- W2317814896 date "2011-05-27" @default.
- W2317814896 modified "2023-10-06" @default.
- W2317814896 title "α-Chalcocite Nanoparticle Synthesis and Stability" @default.
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- W2317814896 doi "https://doi.org/10.1021/cm1031656" @default.
- W2317814896 hasPublicationYear "2011" @default.
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