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- W2317846656 abstract "活性炭電気二重層キャパシタの充放電過程を解析するための基礎として, 速度過程の影響を含まない真の単極容量を測定し, 電解質イオンの蓄電状態を推定した.電極材料を変えても比表面積の相違ほどには静電容量の顕著な変化はなく, 多孔質炭素電極を用いたキャパシタでは, 電極の全表面が電気二重層の形成に必ずしも有効ではないとみられる.種々の電解液を用いたところ, いずれの正塩水溶液でも同程度の静電容量を示したのに対し, 酸水溶液の場合はその2～3倍の値となったが, 電解液濃度を低くすると正塩水溶液と酸水溶液の静電容量の差はほとんどなくなった.水和イオン半径から判断すると, イオンは水和水を伴った状態で蓄電されると考えられるが, 酸水溶液の濃度がある程度高い場合には, プロトントランスファーに起因する陽電荷の電極表面への接近や水和構造の破壊が起こるとみられる." @default.
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- W2317846656 date "1997-01-01" @default.
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- W2317846656 title "Single-Electrode Capacitance and Charged State in Interfacial Region within Nano-Porous Carbon Electrode for Electric Double Layer Capacitor." @default.
- W2317846656 doi "https://doi.org/10.1252/kakoronbunshu.23.512" @default.
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